Literature DB >> 26963892

Tetracene Formation by On-Surface Reduction.

Justus Krüger1, Niko Pavliček2, José M Alonso3, Dolores Pérez3, Enrique Guitián3, Thomas Lehmann1, Gianaurelio Cuniberti1,4, André Gourdon5, Gerhard Meyer2, Leo Gross2, Francesca Moresco1, Diego Peña3.   

Abstract

We present the on-surface reduction of diepoxytetracenes to form genuine tetracene on Cu(111). The conversion is achieved by scanning tunneling microscopy (STM) tip-induced manipulation as well as thermal activation and is conclusively demonstrated by means of atomic force microscopy (AFM) with atomic resolution. We observe that the metallic surface plays an important role in the deoxygenation and for the planarization after bond cleavage.

Entities:  

Keywords:  acenes; atomic force microscopy (AFM); deoxygenation; on-surface reaction; single-molecule chemistry

Year:  2016        PMID： 26963892     DOI： 10.1021/acsnano.6b00505

Source DB:  PubMed          Journal:  ACS Nano        ISSN： 1936-0851            Impact factor:   15.881


  7 in total

1.  On-surface synthesis of heptacene on Ag(001) from brominated and non-brominated tetrahydroheptacene precursors.

Authors:  Luciano Colazzo; Mohammed S G Mohammed; Ruth Dorel; Pawel Nita; Carlos García Fernández; Paula Abufager; Nicolás Lorente; Antonio M Echavarren; Dimas G de Oteyza
Journal:  Chem Commun (Camb)       Date:  2018-09-11       Impact factor: 6.222

2.  Higher Acenes by On-Surface Dehydrogenation: From Heptacene to Undecacene.

Authors:  Rafal Zuzak; Ruth Dorel; Marek Kolmer; Marek Szymonski; Szymon Godlewski; Antonio M Echavarren
Journal:  Angew Chem Int Ed Engl       Date:  2018-06-07       Impact factor: 15.336

3.  On-Surface Synthesis of Ethynylene-Bridged Anthracene Polymers.

Authors:  Ana Sánchez-Grande; Bruno de la Torre; José Santos; Borja Cirera; Koen Lauwaet; Taras Chutora; Shayan Edalatmanesh; Pingo Mutombo; Johanna Rosen; Radek Zbořil; Rodolfo Miranda; Jonas Björk; Pavel Jelínek; Nazario Martín; David Écija
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-12       Impact factor: 15.336

Review 4.  Recent Progress in High Linearly Fused Polycyclic Conjugated Hydrocarbons (PCHs, n > 6) with Well-Defined Structures.

Authors:  Wangqiao Chen; Fei Yu; Qun Xu; Guofu Zhou; Qichun Zhang
Journal:  Adv Sci (Weinh)       Date:  2020-04-22       Impact factor: 16.806

5.  Strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on a copper surface.

Authors:  Akitoshi Shiotari; Takahiro Nakae; Kota Iwata; Shigeki Mori; Tetsuo Okujima; Hidemitsu Uno; Hiroshi Sakaguchi; Yoshiaki Sugimoto
Journal:  Nat Commun       Date:  2017-07-20       Impact factor: 14.919

6.  Mechanical measurement of hydrogen bonded host-guest systems under non-equilibrium, near-physiological conditions.

Authors:  Teresa Naranjo; Fernando Cerrón; Belén Nieto-Ortega; Alfonso Latorre; Álvaro Somoza; Borja Ibarra; Emilio M Pérez
Journal:  Chem Sci       Date:  2017-07-31       Impact factor: 9.825

7.  Three-dimensional graphene nanoribbons as a framework for molecular assembly and local probe chemistry.

Authors:  Shigeki Kawai; Ondřej Krejčí; Tomohiko Nishiuchi; Keisuke Sahara; Takuya Kodama; Rémy Pawlak; Ernst Meyer; Takashi Kubo; Adam S Foster
Journal:  Sci Adv       Date:  2020-02-28       Impact factor: 14.136
  7 in total

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