Literature DB >> 26954722

A Stable Heterocyclic Amino(phosphanylidene-σ(4)-phosphorane) Germylene.

Natalia Del Rio1, Antoine Baceiredo1, Nathalie Saffon-Merceron2, Daisuke Hashizume3, Dennis Lutters4, Thomas Müller4, Tsuyoshi Kato5.   

Abstract

A new stable heterocyclic germylene, in which the divalent germanium atom lies between a nitrogen atom and a phosphanylidene phosphorane group, was synthesized. Experimental and theoretical studies revealed the peculiar effect of phosphanylidene phosphorane substituent, which is a stronger π-donor towards germanium than an amino group is. Because of the weak phosphorus-germanium π-bond, this new germylene compound shows an enhanced reactivity compared to classical N-heterocyclic germylenes.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  germanium; main-group elements; multiple bonds; small-ring compounds; structure elucidation

Year:  2016        PMID： 26954722     DOI： 10.1002/anie.201511956

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.

Authors:  Henning Steinert; Julian Löffler; Viktoria H Gessner
Journal:  Eur J Inorg Chem       Date:  2021-10-26       Impact factor: 2.551

2.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

3.  (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.

Authors:  Max M Hansmann; David A Ruiz; Liu Leo Liu; Rodolphe Jazzar; Guy Bertrand
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

4.  HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.

Authors:  Alexander Hinz; René Labbow; Chris Rennick; Axel Schulz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2017-03-02       Impact factor: 15.336

5.  Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment.

Authors:  Chandrajeet Mohapatra; Lennart T Scharf; Thorsten Scherpf; Bert Mallick; Kai-Stephan Feichtner; Christopher Schwarz; Viktoria H Gessner
Journal:  Angew Chem Int Ed Engl       Date:  2019-04-17       Impact factor: 15.336

6.  Bis-Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

Authors:  Mahendra K Sharma; Pratima Dhawan; Christoph Helling; Christoph Wölper; Stephan Schulz
Journal:  Chemistry       Date:  2022-03-14       Impact factor: 5.020

7.  Reductive Elimination at Pb(II) Center of an (Amino)plumbylene-Substituted Phosphaketene: New Pathway for Phosphinidene Synthesis.

Authors:  Vladislava Timofeeva; José Miguel Léon Baeza; Raphael Nougué; Mikhail Syroeshkin; Rene Segundo Rojas Guerrero; Nathalie Saffon-Merceron; Gül Altınbaş Özpınar; Saskia Rathjen; Thomas Müller; Antoine Baceiredo; Tsuyoshi Kato
Journal:  Chemistry       Date:  2022-06-15       Impact factor: 5.020

8.  Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene.

Authors:  Daniel W N Wilson; Mauricio P Franco; William K Myers; John E McGrady; Jose M Goicoechea
Journal:  Chem Sci       Date:  2019-12-02       Impact factor: 9.825

Review 9.  Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.

Authors:  Abir Sarbajna; V S V S N Swamy; Viktoria H Gessner
Journal:  Chem Sci       Date:  2020-07-17       Impact factor: 9.825

10.  Selective Arylation of 2-Bromo-4-chlorophenyl-2-bromobutanoate via a Pd-Catalyzed Suzuki Cross-Coupling Reaction and Its Electronic and Non-Linear Optical (NLO) Properties via DFT Studies.

Authors:  Usman Nazeer; Nasir Rasool; Aqsa Mujahid; Asim Mansha; Muhammad Zubair; Naveen Kosar; Tariq Mahmood; Ali Raza Shah; Syed Adnan Ali Shah; Zainul Amiruddin Zakaria; Muhammad Nadeem Akhtar
Journal:  Molecules       Date:  2020-07-31       Impact factor: 4.411
  10 in total

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