Literature DB >> 26951759

Reductive debromination of 1,2-dibromides with anisidines.

Kristen M McGraw1, Jeannette T Bowler1, Vy T Ly1, Ihsan Erden1, Weiming Wu1.   

Abstract

vic -Dibromides containing the α-bromocarbonyl or α-bromoaromatic moieties were reductively debrominated to furnish alkenes in high yield. o- and m-Anisidines but not p-anisidine were found to be effective debrominating agents. The reductive debrominations were found to be trans-stereospecific.

Entities:  

Keywords:  Anisidine; Debromination; Redution; vic-Dibromides

Year:  2016        PMID： 26951759      PMCID： PMC4778248          DOI： 10.1016/j.tetlet.2015.11.106

Source DB:  PubMed          Journal:  Tetrahedron Lett        ISSN： 0040-4039            Impact factor:   2.415


  2 in total

1.  Convenient synthesis of N1-substituted orotic acid derivatives.

Authors:  Jeannette T Bowler; Caitlin R Clausen; Daniel J Blackburn; Weiming Wu
Journal:  Tetrahedron Lett       Date:  2014-11-19       Impact factor: 2.415

2.  Radical mechanisms in chromous ion reductions. An improved synthesis of 11-beta-hydroxy steroids.

Authors:  D H Barton; N K Basu; R H Hesse; F S Morehouse; M M Pechet
Journal:  J Am Chem Soc       Date:  1966-07-05       Impact factor: 15.419
  2 in total
  1 in total

1.  cis-β-Bromostyrene derivatives from cinnamic acids via a tandem substitutive bromination-decarboxylation sequence.

Authors:  Khanh G Tang; Greggory T Kent; Ihsan Erden; Weiming Wu
Journal:  Tetrahedron Lett       Date:  2017-08-31       Impact factor: 2.415
  1 in total

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