| Literature DB >> 26949977 |
Oleg A Khakhel'1, Tamila P Romashko1.
Abstract
There are several types of the ΔH compensation. Along with well-known phenomenon of the ΔH - ΔS compensation, two more types of the ΔH - (ΔS + RΔ ln Ω) compensation are observed in some series of systems. The nature of these phenomena is connected with the behavior of phase volume of systems, Ω. The role of other thermodynamic parameters, which describe series in manifestation of this or that types of the ΔH compensation, is shown in light of molecular statistical mechanics.Entities:
Year: 2016 PMID： 26949977 DOI： 10.1021/acs.jpca.6b00493
Source DB: PubMed Journal: J Phys Chem A ISSN： 1089-5639 Impact factor: 2.781