Literature DB >> 26949917

Cyclopentadiene-mediated hydride transfer from rhodium complexes.

C L Pitman1, O N L Finster1, A J M Miller1.   

Abstract

Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C-H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD(+).

Entities:  

Year:  2016        PMID： 26949917     DOI： 10.1039/c6cc00575f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene.

Authors:  Zachary Call; Meagan Suchewski; Christopher A Bradley
Journal:  J Vis Exp       Date:  2017-03-20       Impact factor: 1.355

2.  Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring p Ka Effects and Demonstrating Electrocatalysis.

Authors:  Matthew J Chalkley; Trevor J Del Castillo; Benjamin D Matson; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2018-05-02       Impact factor: 15.419

3.  Evidence for Charge Delocalization in Diazafluorene Ligands Supporting Low-Valent [Cp*Rh] Complexes.

Authors:  Wade C Henke; Jonah P Stiel; Victor W Day; James D Blakemore
Journal:  Chemistry       Date:  2022-01-27       Impact factor: 5.236

4.  Computational studies on the hydride transfer barrier for the catalytic hydrogenation of CO2 by different Ni(II) complexes.

Authors:  Santu Biswas; Animesh Chowdhury; Prodyut Roy; Anup Pramanik; Pranab Sarkar
Journal:  J Mol Model       Date:  2018-08-07       Impact factor: 1.810

5.  Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET.

Authors:  Matthew J Chalkley; Trevor J Del Castillo; Benjamin D Matson; Joseph P Roddy; Jonas C Peters
Journal:  ACS Cent Sci       Date:  2017-02-14       Impact factor: 14.553

6.  New activation mechanism for half-sandwich organometallic anticancer complexes.

Authors:  Samya Banerjee; Joan J Soldevila-Barreda; Juliusz A Wolny; Christopher A Wootton; Abraha Habtemariam; Isolda Romero-Canelón; Feng Chen; Guy J Clarkson; Ivan Prokes; Lijiang Song; Peter B O'Connor; Volker Schünemann; Peter J Sadler
Journal:  Chem Sci       Date:  2018-03-01       Impact factor: 9.825

7.  Single-Electron Redox Chemistry on the [Cp*Rh] Platform Enabled by a Nitrated Bipyridyl Ligand.

Authors:  William N G Moore; Wade C Henke; Davide Lionetti; Victor W Day; James D Blakemore
Journal:  Molecules       Date:  2018-11-02       Impact factor: 4.411

Review 8.  Unraveling the Light-Activated Reaction Mechanism in a Catalytically Competent Key Intermediate of a Multifunctional Molecular Catalyst for Artificial Photosynthesis.

Authors:  Linda Zedler; Alexander Klaus Mengele; Karl Michael Ziems; Ying Zhang; Maria Wächtler; Stefanie Gräfe; Torbjörn Pascher; Sven Rau; Stephan Kupfer; Benjamin Dietzek
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-19       Impact factor: 15.336

9.  Graphite Conjugation Eliminates Redox Intermediates in Molecular Electrocatalysis.

Authors:  Megan N Jackson; Corey J Kaminsky; Seokjoon Oh; Jonathan F Melville; Yogesh Surendranath
Journal:  J Am Chem Soc       Date:  2019-08-29       Impact factor: 15.419

10.  Base-Promoted, Remote C-H Activation at a Cationic (η5-C5Me5)Ir(III) Center Involving Reversible C-C Bond Formation of Bound C5Me5.

Authors:  Juan J Moreno; María F Espada; Jesús Campos; Joaquín López-Serrano; Stuart A Macgregor; Ernesto Carmona
Journal:  J Am Chem Soc       Date:  2019-02-05       Impact factor: 15.419
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