Literature DB >> 26949004

Biomimetic Synthesis of Moschamine-Related Indole Alkaloids via Iron-Catalyzed Selectively Oxidative Radical Coupling.

Kangjiang Liang1,2, Jing Yang1, Xiaogang Tong1, Wenbin Shang1,2, Zhiqiang Pan1, Chengfeng Xia1,3.   

Abstract

An iron-catalyzed oxidative radical coupling reaction was developed to selectively construct indolofuran or bisphenolic indole cores, which exist in two types of moschamine-related indole alkaloids. Both (+)-decursivine and 4,4″-bis(N-feruloyl)serotonin were biomimetically synthesized by using coupling reactions. The proposed reassignment of the structure of montamine as 4,4″-bis(N-feruloyl)serotonin was excluded.

Entities:  

Mesh:

Substances:

Year:  2016        PMID: 26949004     DOI: 10.1021/acs.orglett.6b00417

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Iron-Catalyzed Oxidative C-C Cross-Coupling Reaction of Tertiary Anilines with Hydroxyarenes by Using Air as Sole Oxidant.

Authors:  Alexander Purtsas; Olga Kataeva; Hans-Joachim Knölker
Journal:  Chemistry       Date:  2020-02-04       Impact factor: 5.236

2.  Total synthesis of (±)-decursivine via BINOL-phosphoric acid catalyzed tandem oxidative cyclization.

Authors:  Prakash T Parvatkar; Eugene S Smotkin; Roman Manetsch
Journal:  Sci Rep       Date:  2021-10-07       Impact factor: 4.379

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.