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Literature DB >> 26935207

The ruthenium-catalysed selective synthesis of mono-deuterated terminal alkynes.

Basujit Chatterjee¹, Chidambaram Gunanathan¹.

Abstract

We report an efficient catalytic method for the synthesis of mono-deuterated terminal alkynes directly from deuterium oxide, catalysed by a Ru(II) pincer complex in which the reaction proceeds via Ru-acetylide intermediates and amine-amide metal-ligand cooperation.

Entities: Chemical

Year: 2016 PMID： 26935207 DOI： 10.1039/c6cc01401a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

2 in total

1. Iridium-catalyzed α-selective deuteration of alcohols.

Authors: Moeko Itoga; Masako Yamanishi; Taro Udagawa; Ayane Kobayashi; Keiko Maekawa; Yoshiji Takemoto; Hiroshi Naka
Journal: Chem Sci Date: 2022-07-06 Impact factor: 9.969

2. Practical approaches to labelling terminal alkynes with deuterium.

Authors: Melanie Y T Chan; Arbab Anwar; William J S Lockley
Journal: J Labelled Comp Radiopharm Date: 2022-02-02 Impact factor: 1.949

2 in total