Literature DB >> 26928852

Homoleptic gold(i) N-heterocyclic allenylidene complexes: excited-state properties and lyotropic chromonics.

Xin-Shan Xiao1, Chao Zou2, Xiangguo Guan1, Chen Yang1, Wei Lu2, Chi-Ming Che1.   

Abstract

A series of phosphorescent Au(i) bis(N-heterocyclic allenylidene) complexes, namely [Au(=C=C=CR(1)R(2))2](+)X(-), were synthesized and structurally characterized. These organometallic complexes exhibit panchromatic transient absorption upon electronic photo-excitation and can self-organize into lyotropic chromonic mesophases in aqueous solutions.

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Year:  2016        PMID: 26928852     DOI: 10.1039/c5cc09571a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes.

Authors:  Nana Kim; Ross A Widenhoefer
Journal:  Chem Sci       Date:  2019-05-10       Impact factor: 9.825

2.  Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects.

Authors:  Diego Sorbelli; Laura Nunes Dos Santos Comprido; Gerald Knizia; A Stephen K Hashmi; Leonardo Belpassi; Paola Belanzoni; Johannes E M N Klein
Journal:  Chemphyschem       Date:  2019-06-13       Impact factor: 3.102

  2 in total

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