Literature DB >> 26899945

Catalytic selective deuteration of halo(hetero)arenes.

Manojkumar Janni1, S Peruncheralathan.   

Abstract

Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially available and inexpensive reagents. Selective deuteration of bromoaniline is also demonstrated without H/D exchange in an amino N-H group.

Entities:  

Year:  2016        PMID: 26899945     DOI: 10.1039/c6ob00193a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  5 in total

1.  Synthesis of 2-D-L-Tryptophan by Sequential Ir-Catalyzed Reactions.

Authors:  Ravikrishna Vallakati; Abel T Plotnikov; Ryan A Altman
Journal:  Tetrahedron       Date:  2019-02-26       Impact factor: 2.457

2.  Facile and general electrochemical deuteration of unactivated alkyl halides.

Authors:  Pengfei Li; Chengcheng Guo; Siyi Wang; Dengke Ma; Tian Feng; Yanwei Wang; Youai Qiu
Journal:  Nat Commun       Date:  2022-06-30       Impact factor: 17.694

3.  Controllable deuteration of halogenated compounds by photocatalytic D2O splitting.

Authors:  Cuibo Liu; Zhongxin Chen; Chenliang Su; Xiaoxu Zhao; Qiang Gao; Guo-Hong Ning; Hai Zhu; Wei Tang; Kai Leng; Wei Fu; Bingbing Tian; Xinwen Peng; Jing Li; Qing-Hua Xu; Wu Zhou; Kian Ping Loh
Journal:  Nat Commun       Date:  2018-01-08       Impact factor: 14.919

4.  Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions.

Authors:  Hawraz I M Amin; Carlotta Raviola; Ahmed A Amin; Barbara Mannucci; Stefano Protti; Maurizio Fagnoni
Journal:  Molecules       Date:  2019-06-08       Impact factor: 4.411

5.  Light-driven decarboxylative deuteration enabled by a divergently engineered photodecarboxylase.

Authors:  Jian Xu; Jiajie Fan; Yujiao Lou; Weihua Xu; Zhiguo Wang; Danyang Li; Haonan Zhou; Xianfu Lin; Qi Wu
Journal:  Nat Commun       Date:  2021-06-25       Impact factor: 14.919

  5 in total

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