Crystal structure of 3-(prop-2-en-1-yl)-1-{[(1E)-1,2,3,4-tetra-hydro-naphthalen-1-yl-idene]amino}-thio-urea.

In the title compound, C14H17N3S, the dihedral angle between the planes of the benzene ring and the thio-semicarbazone group (r.m.s. deviation = 0.031 Å) is 8.45 (4)°. A short intra-molcular N-H⋯N contact is seen. In the crystal, weak N-H⋯S hydrogen bonds connect the mol-ecules into C(4) chains propagating in the [010] direction, with adjacent mol-ecules in the chain related by 21 screw-axis symmetry.

Related literature

For a related structure and background to thio­semi­car­ba­zones, see: Mohamed et al. (2015 ▸). For further synthetic details, see: Mague et al. (2014 ▸).

Experimental

Crystal data

C14H17N3S

M = 259.36

Monoclinic,

a = 7.6665 (2) Å

b = 8.5788 (2) Å

c = 20.4072 (5) Å

β = 91.794 (1)°

V = 1341.51 (6) Å3

Z = 4

Cu Kα radiation

μ = 2.02 mm−1

T = 150 K

0.20 × 0.19 × 0.16 mm

Data collection

Bruker D8 VENTURE PHOTON 100 CMOS diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2014 ▸) T min = 0.68, T max = 0.73

10141 measured reflections

2687 independent reflections

2486 reflections with I > 2σ(I)

R int = 0.022

Refinement

R[F 2 > 2σ(F 2)] = 0.031

wR(F 2) = 0.084

S = 1.07

2687 reflections

163 parameters

H-atom parameters constrained

Δρmax = 0.25 e Å−3

Δρmin = −0.24 e Å−3

Data collection: APEX2 (Bruker, 2014 ▸); cell refinement: SAINT (Bruker, 2014 ▸); data reduction: SAINT; program(s) used to solve structure: SHELXT (Bruker, 2014 ▸); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015 ▸); molecular graphics: DIAMOND (Brandenburg & Putz, 2012 ▸); software used to prepare material for publication: SHELXTL (Bruker, 2014 ▸).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S2056989015021076/hb7539sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015021076/hb7539Isup2.hkl

Click here for additional data file.

Supporting information file. DOI: 10.1107/S2056989015021076/hb7539Isup3.cml

Click here for additional data file.

. DOI: 10.1107/S2056989015021076/hb7539fig1.tif

The title mol­ecule with 50% probability displacement ellipsoids.

Click here for additional data file.

a . DOI: 10.1107/S2056989015021076/hb7539fig2.tif

Packing viewed down the a axis.

CCDC reference: 1435398

Additional supporting information: crystallographic information; 3D view; checkCIF report

C14H17N3S	F(000) = 552
Mr = 259.36	Dx = 1.284 Mg m−3
Monoclinic, P21/n	Cu Kα radiation, λ = 1.54178 Å
a = 7.6665 (2) Å	Cell parameters from 8207 reflections
b = 8.5788 (2) Å	θ = 4.3–74.5°
c = 20.4072 (5) Å	µ = 2.02 mm−1
β = 91.794 (1)°	T = 150 K
V = 1341.51 (6) Å3	Block, colourless
Z = 4	0.20 × 0.19 × 0.16 mm

Bruker D8 VENTURE PHOTON 100 CMOS diffractometer	2687 independent reflections
Radiation source: INCOATEC IµS micro–focus source	2486 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.022
Detector resolution: 10.4167 pixels mm-1	θmax = 74.5°, θmin = 4.3°
ω scans	h = −8→9
Absorption correction: multi-scan (SADABS; Bruker, 2014)	k = −10→10
Tmin = 0.68, Tmax = 0.73	l = −21→25
10141 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031	Hydrogen site location: mixed
wR(F2) = 0.084	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0458P)2 + 0.3454P] where P = (Fo2 + 2Fc2)/3
2687 reflections	(Δ/σ)max = 0.001
163 parameters	Δρmax = 0.25 e Å−3
0 restraints	Δρmin = −0.24 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. H-atoms attached to carbon were placed in calculated positions (C—H = 0.95 - 0.99 Å) while those attached to nitrogen were placed in locations derived from a difference map and their parameters adjusted to give N—H = 0.91 Å. All were included as riding contributions with isotropic displacement parameters 1.2 times those of the attached atoms.

	x	y	z	Uiso*/Ueq
S1	0.48923 (4)	0.32351 (4)	0.80129 (2)	0.03037 (11)
N1	0.24491 (13)	0.48661 (13)	0.73353 (5)	0.0280 (2)
H1N	0.2236	0.5554	0.7003	0.034*
N2	0.51325 (12)	0.47130 (12)	0.68903 (5)	0.0239 (2)
H2N	0.6272	0.4415	0.6911	0.029*
N3	0.44987 (12)	0.56539 (11)	0.63901 (4)	0.0220 (2)
C1	−0.0358 (2)	0.27861 (18)	0.69916 (8)	0.0472 (4)
H1A	0.0572	0.2901	0.6699	0.057*
H1B	−0.1320	0.2131	0.6878	0.057*
C2	−0.03150 (17)	0.35274 (17)	0.75504 (7)	0.0348 (3)
H2	−0.1277	0.3373	0.7826	0.042*
C3	0.10929 (16)	0.45938 (16)	0.78005 (6)	0.0299 (3)
H3A	0.0565	0.5606	0.7917	0.036*
H3B	0.1628	0.4143	0.8206	0.036*
C4	0.40678 (15)	0.43269 (13)	0.73855 (5)	0.0234 (2)
C5	0.55646 (14)	0.60710 (13)	0.59461 (5)	0.0203 (2)
C6	0.74503 (15)	0.55855 (14)	0.59361 (6)	0.0249 (2)
H6A	0.7515	0.4483	0.5795	0.030*
H6B	0.7964	0.5655	0.6386	0.030*
C7	0.85274 (15)	0.65815 (15)	0.54803 (6)	0.0265 (3)
H7A	0.8674	0.7639	0.5669	0.032*
H7B	0.9700	0.6114	0.5440	0.032*
C8	0.76392 (16)	0.66981 (15)	0.48046 (6)	0.0279 (3)
H8A	0.8331	0.7386	0.4522	0.033*
H8B	0.7588	0.5652	0.4600	0.033*
C9	0.58186 (15)	0.73399 (13)	0.48518 (5)	0.0235 (2)
C10	0.50909 (18)	0.82536 (14)	0.43472 (6)	0.0293 (3)
H10	0.5748	0.8447	0.3969	0.035*
C11	0.34410 (18)	0.88813 (14)	0.43851 (6)	0.0323 (3)
H11	0.2971	0.9499	0.4036	0.039*
C12	0.24694 (17)	0.86062 (14)	0.49371 (6)	0.0299 (3)
H12	0.1333	0.9037	0.4966	0.036*
C13	0.31603 (15)	0.77037 (13)	0.54449 (6)	0.0244 (2)
H13	0.2494	0.7522	0.5822	0.029*
C14	0.48339 (15)	0.70551 (13)	0.54080 (5)	0.0208 (2)

	U11	U22	U33	U12	U13	U23
S1	0.02807 (18)	0.03706 (19)	0.02591 (18)	−0.00248 (11)	−0.00050 (12)	0.01231 (11)
N1	0.0248 (5)	0.0385 (6)	0.0208 (5)	−0.0010 (4)	0.0016 (4)	0.0074 (4)
N2	0.0233 (5)	0.0280 (5)	0.0204 (5)	−0.0003 (4)	0.0011 (4)	0.0048 (4)
N3	0.0247 (5)	0.0240 (5)	0.0173 (4)	−0.0012 (4)	−0.0001 (4)	0.0013 (3)
C1	0.0498 (9)	0.0378 (8)	0.0528 (9)	−0.0060 (7)	−0.0182 (7)	0.0063 (7)
C2	0.0252 (6)	0.0413 (7)	0.0378 (7)	−0.0005 (5)	−0.0005 (5)	0.0176 (6)
C3	0.0288 (6)	0.0410 (7)	0.0203 (6)	0.0011 (5)	0.0056 (5)	0.0035 (5)
C4	0.0259 (6)	0.0247 (6)	0.0196 (5)	−0.0047 (4)	0.0001 (4)	−0.0001 (4)
C5	0.0228 (5)	0.0206 (5)	0.0176 (5)	−0.0034 (4)	−0.0004 (4)	−0.0024 (4)
C6	0.0223 (5)	0.0273 (6)	0.0249 (6)	−0.0018 (4)	0.0000 (4)	0.0021 (4)
C7	0.0216 (6)	0.0329 (6)	0.0250 (6)	−0.0057 (5)	0.0012 (5)	−0.0015 (5)
C8	0.0267 (6)	0.0362 (7)	0.0209 (6)	−0.0066 (5)	0.0043 (5)	−0.0025 (4)
C9	0.0278 (6)	0.0230 (5)	0.0198 (5)	−0.0077 (4)	0.0001 (4)	−0.0018 (4)
C10	0.0389 (7)	0.0298 (6)	0.0192 (6)	−0.0094 (5)	−0.0003 (5)	0.0019 (4)
C11	0.0450 (7)	0.0239 (6)	0.0272 (6)	−0.0038 (5)	−0.0098 (5)	0.0041 (5)
C12	0.0315 (6)	0.0237 (6)	0.0339 (7)	0.0025 (5)	−0.0068 (5)	−0.0013 (5)
C13	0.0263 (6)	0.0233 (5)	0.0235 (6)	−0.0024 (4)	0.0005 (4)	−0.0016 (4)
C14	0.0238 (5)	0.0198 (5)	0.0186 (5)	−0.0039 (4)	−0.0014 (4)	−0.0018 (4)

S1—C4	1.6928 (12)	C6—H6A	0.9900
N1—C4	1.3254 (16)	C6—H6B	0.9900
N1—C3	1.4487 (16)	C7—C8	1.5220 (16)
N1—H1N	0.9098	C7—H7A	0.9900
N2—C4	1.3597 (15)	C7—H7B	0.9900
N2—N3	1.3778 (13)	C8—C9	1.5063 (17)
N2—H2N	0.9098	C8—H8A	0.9900
N3—C5	1.2897 (15)	C8—H8B	0.9900
C1—C2	1.305 (2)	C9—C10	1.3964 (17)
C1—H1A	0.9500	C9—C14	1.4042 (16)
C1—H1B	0.9500	C10—C11	1.379 (2)
C2—C3	1.4926 (19)	C10—H10	0.9500
C2—H2	0.9500	C11—C12	1.390 (2)
C3—H3A	0.9900	C11—H11	0.9500
C3—H3B	0.9900	C12—C13	1.3854 (17)
C5—C14	1.4811 (15)	C12—H12	0.9500
C5—C6	1.5052 (16)	C13—C14	1.4027 (16)
C6—C7	1.5249 (16)	C13—H13	0.9500
C4—N1—C3	125.63 (10)	C8—C7—C6	110.73 (10)
C4—N1—H1N	115.4	C8—C7—H7A	109.5
C3—N1—H1N	118.5	C6—C7—H7A	109.5
C4—N2—N3	119.17 (10)	C8—C7—H7B	109.5
C4—N2—H2N	119.7	C6—C7—H7B	109.5
N3—N2—H2N	121.0	H7A—C7—H7B	108.1
C5—N3—N2	117.81 (10)	C9—C8—C7	110.81 (10)
C2—C1—H1A	120.0	C9—C8—H8A	109.5
C2—C1—H1B	120.0	C7—C8—H8A	109.5
H1A—C1—H1B	120.0	C9—C8—H8B	109.5
C1—C2—C3	126.56 (14)	C7—C8—H8B	109.5
C1—C2—H2	116.7	H8A—C8—H8B	108.1
C3—C2—H2	116.7	C10—C9—C14	118.77 (11)
N1—C3—C2	113.63 (11)	C10—C9—C8	120.51 (11)
N1—C3—H3A	108.8	C14—C9—C8	120.71 (10)
C2—C3—H3A	108.8	C11—C10—C9	121.58 (12)
N1—C3—H3B	108.8	C11—C10—H10	119.2
C2—C3—H3B	108.8	C9—C10—H10	119.2
H3A—C3—H3B	107.7	C10—C11—C12	119.66 (11)
N1—C4—N2	116.10 (10)	C10—C11—H11	120.2
N1—C4—S1	125.31 (9)	C12—C11—H11	120.2
N2—C4—S1	118.58 (9)	C13—C12—C11	119.94 (12)
N3—C5—C14	116.47 (10)	C13—C12—H12	120.0
N3—C5—C6	124.24 (10)	C11—C12—H12	120.0
C14—C5—C6	119.26 (10)	C12—C13—C14	120.69 (11)
C5—C6—C7	113.07 (10)	C12—C13—H13	119.7
C5—C6—H6A	109.0	C14—C13—H13	119.7
C7—C6—H6A	109.0	C13—C14—C9	119.35 (10)
C5—C6—H6B	109.0	C13—C14—C5	120.78 (10)
C7—C6—H6B	109.0	C9—C14—C5	119.87 (10)
H6A—C6—H6B	107.8
C4—N2—N3—C5	176.28 (10)	C14—C9—C10—C11	0.25 (17)
C4—N1—C3—C2	−109.16 (14)	C8—C9—C10—C11	−178.62 (11)
C1—C2—C3—N1	4.4 (2)	C9—C10—C11—C12	0.07 (18)
C3—N1—C4—N2	179.56 (11)	C10—C11—C12—C13	−0.07 (18)
C3—N1—C4—S1	−1.23 (18)	C11—C12—C13—C14	−0.26 (18)
N3—N2—C4—N1	1.89 (16)	C12—C13—C14—C9	0.58 (17)
N3—N2—C4—S1	−177.38 (8)	C12—C13—C14—C5	−179.10 (10)
N2—N3—C5—C14	178.78 (9)	C10—C9—C14—C13	−0.57 (16)
N2—N3—C5—C6	0.54 (16)	C8—C9—C14—C13	178.30 (10)
N3—C5—C6—C7	−163.89 (11)	C10—C9—C14—C5	179.12 (10)
C14—C5—C6—C7	17.91 (14)	C8—C9—C14—C5	−2.02 (16)
C5—C6—C7—C8	−50.50 (14)	N3—C5—C14—C13	10.37 (15)
C6—C7—C8—C9	56.66 (13)	C6—C5—C14—C13	−171.29 (10)
C7—C8—C9—C10	147.83 (11)	N3—C5—C14—C9	−169.31 (10)
C7—C8—C9—C14	−31.02 (15)	C6—C5—C14—C9	9.03 (15)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1N···N3	0.91	2.17	2.6146 (13)	109
N1—H1N···S1i	0.91	2.82	3.4642 (11)	129

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1N⋯N3	0.91	2.17	2.6146 (13)	109
N1—H1N⋯S1i	0.91	2.82	3.4642 (11)	129

Symmetry code: (i) .