Crystal structure of ethyl 2-{2-[(1Z)-1-hy-droxy-3-(4-nitro-phen-yl)-3-oxoprop-1-en-1-yl]phen-oxy}acetate.

The title compound, C19H17NO7, crystallized in a ratio of about 6:4 of the two possible keto-enol forms. This was observed as disorder over the central C3H2O2 unit. The dihedral angle between the rings is 8.2 (2)°.The mol-ecules pack by C-H⋯O interactions in a layered fashion parallel to (-104).

Related literature

For the use of aryl­oxyphen­oxy compounds in various herbicidal applications, see: Zhu et al. (2006 ▸, 2009 ▸); Li (2004 ▸); Wang et al. (2004 ▸). For the synthesis of the title compund, see: Akkurt et al. (2015 ▸).

Experimental

Crystal data

C19H17NO7

M = 371.33

Monoclinic,

a = 4.7818 (10) Å

b = 16.260 (3) Å

c = 21.948 (5) Å

β = 95.933 (3)°

V = 1697.4 (6) Å3

Z = 4

Mo Kα radiation

μ = 0.11 mm−1

T = 150 K

0.24 × 0.08 × 0.03 mm

Data collection

Bruker SMART APEX CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2014 ▸) T min = 0.60, T max = 1.00

15039 measured reflections

3952 independent reflections

1800 reflections with I > 2σ(I)

R int = 0.116

Refinement

R[F 2 > 2σ(F 2)] = 0.072

wR(F 2) = 0.194

S = 1.00

3952 reflections

245 parameters

H-atom parameters constrained

Δρmax = 0.23 e Å−3

Δρmin = −0.29 e Å−3

Data collection: APEX2 (Bruker, 2014 ▸); cell refinement: SAINT (Bruker, 2014 ▸); data reduction: SAINT; program(s) used to solve structure: SHELXT (Sheldrick, 2015a ▸); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b ▸); molecular graphics: DIAMOND (Brandenburg & Putz, 2012 ▸); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 ▸).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S2056989015020794/qm2113sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015020794/qm2113Isup2.hkl

Click here for additional data file.

Supporting information file. DOI: 10.1107/S2056989015020794/qm2113Isup3.cml

Click here for additional data file.

A . DOI: 10.1107/S2056989015020794/qm2113fig1.tif

The title mol­ecule with labeling scheme and 50% probability ellipsoids. Only one location (H4A) of the disordered enol hydrogen is shown. Intra­molecular hydrogen bonds are shown by dotted lines.

Click here for additional data file.

a . DOI: 10.1107/S2056989015020794/qm2113fig2.tif

Packing viewed down the a axis. Inter­molecular C—H⋯O hydrogen bonds are shown by dotted lines.

Click here for additional data file.

b . DOI: 10.1107/S2056989015020794/qm2113fig3.tif

Packing viewed down the b axis showing the layered structure.

CCDC reference: 1434730

Additional supporting information: crystallographic information; 3D view; checkCIF report

C19H17NO7	F(000) = 776
Mr = 371.33	Dx = 1.453 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 4.7818 (10) Å	Cell parameters from 2496 reflections
b = 16.260 (3) Å	θ = 2.3–26.7°
c = 21.948 (5) Å	µ = 0.11 mm−1
β = 95.933 (3)°	T = 150 K
V = 1697.4 (6) Å3	Column, pale yellow
Z = 4	0.24 × 0.08 × 0.03 mm

Bruker SMART APEX CCD diffractometer	3952 independent reflections
Radiation source: fine-focus sealed tube	1800 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.116
Detector resolution: 8.3660 pixels mm-1	θmax = 27.9°, θmin = 1.6°
φ and ω scans	h = −6→6
Absorption correction: multi-scan (SADABS; Bruker, 2014)	k = −20→20
Tmin = 0.60, Tmax = 1.00	l = −28→28
15039 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.072	Hydrogen site location: mixed
wR(F2) = 0.194	H-atom parameters constrained
S = 1.00	w = 1/[σ2(Fo2) + (0.0701P)2 + 0.4312P] where P = (Fo2 + 2Fc2)/3
3952 reflections	(Δ/σ)max < 0.001
245 parameters	Δρmax = 0.23 e Å−3
0 restraints	Δρmin = −0.29 e Å−3

Experimental. The diffraction data were collected in three sets of 363 frames (0.5° width in ω) at φ = 0, 120 and 240°. A scan time of 120 sec/frame was used.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. H-atoms attached to carbon were placed in calculated positions (C—H = 0.95 - 0.99 Å). All were included as riding contributions with isotropic displacement parameters 1.2 - 1.5 times those of the attached atoms. From the equivalence of the C7—C8 and C8—C9 bond distances, the near equivalence of the C7—O3 and C9—O4 bond distances and the observance of only one peak attributable to a hydrogen attached to C8 in a difference map, it was concluded that the compound exists as the keto-enol tautomer with the enol hydrogen disordered between O3 and O4. Contoured difference maps calculated in the region between O3 and O4 showed an elongated region of density consistent with this assumption. The two components of the disordered hydrogen (H3a and H4a) were placed in positions consistent with forming intramolecular O—H···O hydrogen bonds and allowed to ride on the respective oxygen atoms.

	x	y	z	Uiso*/Ueq	Occ. (<1)
O1	1.3713 (6)	0.88831 (19)	0.52969 (13)	0.0660 (9)
O2	1.3341 (6)	0.75575 (19)	0.52420 (12)	0.0568 (8)
O3	0.2970 (5)	0.93367 (15)	0.30167 (11)	0.0469 (7)
H3A	0.1539	0.9368	0.2746	0.070*	0.4
O4	−0.0854 (5)	0.88128 (16)	0.23034 (12)	0.0559 (8)
H4A	0.0513	0.9093	0.2485	0.084*	0.6
O5	−0.0494 (5)	0.63587 (13)	0.28606 (10)	0.0391 (6)
O6	0.3347 (6)	0.58820 (15)	0.37708 (13)	0.0575 (8)
O7	0.1989 (6)	0.45723 (15)	0.36325 (12)	0.0539 (8)
N1	1.2619 (7)	0.8252 (2)	0.50788 (14)	0.0482 (9)
C1	0.5850 (7)	0.8492 (2)	0.36892 (15)	0.0324 (8)
C2	0.7260 (7)	0.9186 (2)	0.39276 (17)	0.0412 (9)
H2	0.6703	0.9715	0.3775	0.049*
C3	0.9464 (8)	0.9116 (2)	0.43836 (17)	0.0451 (10)
H3	1.0410	0.9591	0.4551	0.054*
C4	1.0263 (7)	0.8345 (2)	0.45906 (15)	0.0368 (9)
C5	0.8938 (7)	0.7638 (2)	0.43615 (16)	0.0398 (9)
H5	0.9535	0.7112	0.4510	0.048*
C6	0.6703 (7)	0.7720 (2)	0.39061 (15)	0.0372 (9)
H6	0.5753	0.7244	0.3742	0.045*
C7	0.3471 (7)	0.8596 (2)	0.31935 (15)	0.0321 (8)
C8	0.1895 (7)	0.7929 (2)	0.29482 (15)	0.0329 (8)
H8	0.2333	0.7388	0.3091	0.039*
C9	−0.0329 (7)	0.8058 (2)	0.24920 (15)	0.0331 (8)
C10	−0.2205 (7)	0.7428 (2)	0.21933 (15)	0.0327 (8)
C11	−0.4082 (7)	0.7682 (2)	0.16947 (15)	0.0384 (9)
H11	−0.4063	0.8241	0.1568	0.046*
C12	−0.5941 (7)	0.7148 (2)	0.13854 (16)	0.0440 (10)
H12	−0.7185	0.7339	0.1049	0.053*
C13	−0.6003 (8)	0.6340 (2)	0.15610 (16)	0.0448 (10)
H13	−0.7287	0.5969	0.1347	0.054*
C14	−0.4184 (8)	0.6064 (2)	0.20538 (16)	0.0437 (10)
H14	−0.4233	0.5505	0.2177	0.052*
C15	−0.2297 (7)	0.6604 (2)	0.23651 (15)	0.0353 (8)
C16	−0.0496 (8)	0.5517 (2)	0.30174 (16)	0.0397 (9)
H16A	−0.0199	0.5176	0.2656	0.048*
H16B	−0.2324	0.5363	0.3160	0.048*
C17	0.1850 (8)	0.5374 (2)	0.35214 (16)	0.0384 (9)
C18	0.4091 (8)	0.4278 (2)	0.41157 (17)	0.0489 (10)
H18A	0.5634	0.4683	0.4186	0.059*
H18B	0.4899	0.3751	0.3990	0.059*
C19	0.2724 (9)	0.4159 (3)	0.46874 (18)	0.0589 (12)
H19A	0.1949	0.4683	0.4812	0.088*
H19B	0.4117	0.3959	0.5013	0.088*
H19C	0.1205	0.3755	0.4615	0.088*

	U11	U22	U33	U12	U13	U23
O1	0.0585 (19)	0.076 (2)	0.0572 (19)	−0.0132 (17)	−0.0234 (15)	−0.0046 (17)
O2	0.0511 (18)	0.073 (2)	0.0420 (16)	0.0133 (15)	−0.0162 (13)	0.0053 (15)
O3	0.0465 (15)	0.0384 (15)	0.0514 (17)	−0.0023 (12)	−0.0164 (13)	0.0115 (12)
O4	0.0570 (18)	0.0470 (17)	0.0582 (18)	−0.0019 (14)	−0.0211 (14)	0.0137 (14)
O5	0.0443 (15)	0.0320 (14)	0.0364 (14)	0.0022 (11)	−0.0179 (12)	0.0032 (11)
O6	0.0611 (18)	0.0403 (16)	0.0629 (19)	−0.0073 (14)	−0.0321 (15)	0.0070 (14)
O7	0.0628 (18)	0.0381 (16)	0.0534 (17)	0.0016 (13)	−0.0295 (14)	0.0066 (13)
N1	0.0387 (19)	0.073 (3)	0.0314 (18)	−0.0048 (19)	−0.0042 (15)	−0.0007 (18)
C1	0.0299 (18)	0.037 (2)	0.0298 (18)	0.0020 (16)	−0.0013 (15)	0.0016 (16)
C2	0.039 (2)	0.041 (2)	0.042 (2)	0.0028 (17)	−0.0036 (18)	0.0011 (17)
C3	0.044 (2)	0.047 (3)	0.042 (2)	−0.0021 (19)	−0.0090 (18)	−0.0069 (19)
C4	0.0300 (19)	0.053 (2)	0.0271 (19)	0.0017 (17)	0.0007 (15)	−0.0004 (17)
C5	0.036 (2)	0.045 (2)	0.037 (2)	0.0052 (17)	−0.0063 (17)	0.0045 (18)
C6	0.037 (2)	0.039 (2)	0.035 (2)	−0.0024 (16)	−0.0027 (16)	0.0030 (17)
C7	0.0322 (19)	0.034 (2)	0.0304 (19)	0.0040 (16)	0.0028 (16)	0.0043 (16)
C8	0.0305 (19)	0.036 (2)	0.0309 (19)	0.0050 (15)	−0.0027 (15)	0.0032 (15)
C9	0.0340 (19)	0.035 (2)	0.0303 (19)	0.0039 (16)	0.0014 (16)	0.0063 (16)
C10	0.0294 (19)	0.040 (2)	0.0269 (18)	0.0037 (15)	−0.0052 (14)	−0.0012 (15)
C11	0.0312 (19)	0.046 (2)	0.035 (2)	0.0057 (17)	−0.0073 (16)	0.0066 (17)
C12	0.037 (2)	0.058 (3)	0.034 (2)	0.0027 (19)	−0.0115 (17)	0.0007 (19)
C13	0.043 (2)	0.051 (3)	0.037 (2)	−0.0009 (19)	−0.0102 (18)	−0.0066 (19)
C14	0.047 (2)	0.042 (2)	0.039 (2)	0.0005 (18)	−0.0119 (18)	0.0003 (18)
C15	0.0322 (19)	0.045 (2)	0.0265 (18)	0.0078 (17)	−0.0056 (15)	−0.0019 (17)
C16	0.040 (2)	0.036 (2)	0.039 (2)	0.0007 (17)	−0.0130 (17)	0.0023 (17)
C17	0.045 (2)	0.030 (2)	0.037 (2)	0.0020 (17)	−0.0077 (18)	0.0056 (17)
C18	0.052 (2)	0.048 (2)	0.043 (2)	0.006 (2)	−0.0136 (19)	0.0080 (19)
C19	0.057 (3)	0.068 (3)	0.048 (3)	0.007 (2)	−0.013 (2)	0.000 (2)

O1—N1	1.226 (4)	C7—C8	1.396 (5)
O2—N1	1.224 (4)	C8—C9	1.399 (4)
O3—C7	1.281 (4)	C8—H8	0.9500
O3—H3A	0.8600	C9—C10	1.470 (5)
O4—C9	1.311 (4)	C10—C15	1.394 (5)
O4—H4A	0.8601	C10—C11	1.404 (4)
O5—C15	1.375 (4)	C11—C12	1.371 (5)
O5—C16	1.412 (4)	C11—H11	0.9500
O6—C17	1.189 (4)	C12—C13	1.371 (5)
O7—C17	1.327 (4)	C12—H12	0.9500
O7—C18	1.464 (4)	C13—C14	1.390 (5)
N1—C4	1.480 (4)	C13—H13	0.9500
C1—C6	1.388 (4)	C14—C15	1.387 (5)
C1—C2	1.390 (5)	C14—H14	0.9500
C1—C7	1.500 (5)	C16—C17	1.510 (5)
C2—C3	1.381 (5)	C16—H16A	0.9900
C2—H2	0.9500	C16—H16B	0.9900
C3—C4	1.374 (5)	C18—C19	1.486 (5)
C3—H3	0.9500	C18—H18A	0.9900
C4—C5	1.381 (5)	C18—H18B	0.9900
C5—C6	1.392 (5)	C19—H19A	0.9800
C5—H5	0.9500	C19—H19B	0.9800
C6—H6	0.9500	C19—H19C	0.9800
C7—O3—H3A	112.1	C12—C11—C10	122.0 (3)
C9—O4—H4A	103.8	C12—C11—H11	119.0
C15—O5—C16	117.3 (3)	C10—C11—H11	119.0
C17—O7—C18	118.2 (3)	C13—C12—C11	120.0 (3)
O2—N1—O1	124.2 (3)	C13—C12—H12	120.0
O2—N1—C4	118.4 (3)	C11—C12—H12	120.0
O1—N1—C4	117.4 (3)	C12—C13—C14	119.9 (3)
C6—C1—C2	119.4 (3)	C12—C13—H13	120.1
C6—C1—C7	121.6 (3)	C14—C13—H13	120.1
C2—C1—C7	118.9 (3)	C15—C14—C13	120.1 (4)
C3—C2—C1	120.6 (3)	C15—C14—H14	120.0
C3—C2—H2	119.7	C13—C14—H14	120.0
C1—C2—H2	119.7	O5—C15—C14	121.9 (3)
C4—C3—C2	118.7 (3)	O5—C15—C10	117.3 (3)
C4—C3—H3	120.6	C14—C15—C10	120.8 (3)
C2—C3—H3	120.6	O5—C16—C17	108.0 (3)
C3—C4—C5	122.5 (3)	O5—C16—H16A	110.1
C3—C4—N1	119.8 (3)	C17—C16—H16A	110.1
C5—C4—N1	117.7 (3)	O5—C16—H16B	110.1
C4—C5—C6	118.1 (3)	C17—C16—H16B	110.1
C4—C5—H5	121.0	H16A—C16—H16B	108.4
C6—C5—H5	121.0	O6—C17—O7	125.6 (3)
C1—C6—C5	120.6 (3)	O6—C17—C16	126.7 (3)
C1—C6—H6	119.7	O7—C17—C16	107.7 (3)
C5—C6—H6	119.7	O7—C18—C19	109.0 (3)
O3—C7—C8	122.5 (3)	O7—C18—H18A	109.9
O3—C7—C1	115.5 (3)	C19—C18—H18A	109.9
C8—C7—C1	122.1 (3)	O7—C18—H18B	109.9
C7—C8—C9	120.0 (3)	C19—C18—H18B	109.9
C7—C8—H8	120.0	H18A—C18—H18B	108.3
C9—C8—H8	120.0	C18—C19—H19A	109.5
O4—C9—C8	118.2 (3)	C18—C19—H19B	109.5
O4—C9—C10	115.0 (3)	H19A—C19—H19B	109.5
C8—C9—C10	126.8 (3)	C18—C19—H19C	109.5
C15—C10—C11	117.2 (3)	H19A—C19—H19C	109.5
C15—C10—C9	125.7 (3)	H19B—C19—H19C	109.5
C11—C10—C9	117.0 (3)
C6—C1—C2—C3	−1.1 (5)	C8—C9—C10—C15	8.1 (6)
C7—C1—C2—C3	−179.9 (3)	O4—C9—C10—C11	7.8 (5)
C1—C2—C3—C4	1.0 (6)	C8—C9—C10—C11	−172.5 (3)
C2—C3—C4—C5	−0.2 (6)	C15—C10—C11—C12	0.0 (5)
C2—C3—C4—N1	180.0 (3)	C9—C10—C11—C12	−179.5 (3)
O2—N1—C4—C3	−177.9 (3)	C10—C11—C12—C13	0.0 (6)
O1—N1—C4—C3	2.6 (5)	C11—C12—C13—C14	0.1 (6)
O2—N1—C4—C5	2.3 (5)	C12—C13—C14—C15	−0.4 (6)
O1—N1—C4—C5	−177.2 (3)	C16—O5—C15—C14	4.2 (5)
C3—C4—C5—C6	−0.4 (6)	C16—O5—C15—C10	−177.2 (3)
N1—C4—C5—C6	179.4 (3)	C13—C14—C15—O5	178.9 (3)
C2—C1—C6—C5	0.5 (5)	C13—C14—C15—C10	0.4 (6)
C7—C1—C6—C5	179.2 (3)	C11—C10—C15—O5	−178.8 (3)
C4—C5—C6—C1	0.2 (5)	C9—C10—C15—O5	0.6 (5)
C6—C1—C7—O3	−177.2 (3)	C11—C10—C15—C14	−0.3 (5)
C2—C1—C7—O3	1.6 (5)	C9—C10—C15—C14	179.2 (3)
C6—C1—C7—C8	3.6 (5)	C15—O5—C16—C17	173.6 (3)
C2—C1—C7—C8	−177.7 (3)	C18—O7—C17—O6	2.1 (6)
O3—C7—C8—C9	−0.1 (5)	C18—O7—C17—C16	−178.9 (3)
C1—C7—C8—C9	179.1 (3)	O5—C16—C17—O6	4.0 (6)
C7—C8—C9—O4	0.5 (5)	O5—C16—C17—O7	−175.0 (3)
C7—C8—C9—C10	−179.2 (3)	C17—O7—C18—C19	97.7 (4)
O4—C9—C10—C15	−171.6 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C8—H8···O5	0.95	2.18	2.796 (4)	122
C16—H16A···O3i	0.99	2.35	3.295 (5)	160
O3—H3A···O4	0.86	1.69	2.435 (3)	144
O4—H4A···O3	0.86	1.62	2.435 (3)	158

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C8—H8⋯O5	0.95	2.18	2.796 (4)	122
C16—H16A⋯O3i	0.99	2.35	3.295 (5)	160
O3—H3A⋯O4	0.86	1.69	2.435 (3)	144
O4—H4A⋯O3	0.86	1.62	2.435 (3)	158

Symmetry code: (i) .