Literature DB >> 26865333

Visible light-induced intramolecular dearomative cyclization of α-bromo-N-benzyl-alkylamides: efficient construction of 2-azaspiro[4.5]decanes.

Bei Hu1, Yuyuan Li2, Wuheng Dong1, Kai Ren1, Xiaomin Xie1, Jun Wan2, Zhaoguo Zhang3.   

Abstract

An efficient intramolecular dearomative cyclization via visible light-induced photoredox catalysis allows for a highly regioselective dearomative cyclization of α-bromo-N-benzyl-alkylamides to construct 2-azaspiro[4.5]decanes in the presence of an iridium catalyst.

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Year:  2016        PMID: 26865333     DOI: 10.1039/c5cc09726f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Visible-Light-Induced Dearomatizations.

Authors:  Mikiko Okumura; David Sarlah
Journal:  European J Org Chem       Date:  2019-09-25
  1 in total

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