Literature DB >> 26865194

A Breathing Zirconium Metal-Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation.

Bart Bueken1, Frederik Vermoortele1, Matthew J Cliffe2,3, Michael T Wharmby4,5, Damien Foucher6, Jelle Wieme7, Louis Vanduyfhuys7, Charlotte Martineau6, Norbert Stock4, Francis Taulelle6, Veronique Van Speybroeck7, Andrew L Goodwin2, Dirk De Vos8.   

Abstract

The isoreticular analogue of the metal-organic framework UiO-66(Zr), synthesized with the flexible trans-1,4-cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long-range crystalline order upon evacuation. The underlying flexibility is attributed to a concerted conformational contraction of up to two thirds of the linkers, which breaks the local lattice symmetry. X-ray scattering data are described well by a nanodomain model in which differently oriented tetragonal-type distortions propagate over about 7-10 unit cells.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  dynamic porosity; metal-organic frameworks; phase transitions; structure elucidation; zirconium

Year:  2016        PMID： 26865194     DOI： 10.1002/chem.201600330

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  7 in total

Review 1.  Structural Analysis of Molecular Materials Using the Pair Distribution Function.

Authors:  Maxwell W Terban; Simon J L Billinge
Journal:  Chem Rev       Date:  2021-11-17       Impact factor: 60.622

2.  Thermodynamic Insight in the High-Pressure Behavior of UiO-66: Effect of Linker Defects and Linker Expansion.

Authors:  Sven M J Rogge; Jelle Wieme; Louis Vanduyfhuys; Steven Vandenbrande; Guillaume Maurin; Toon Verstraelen; Michel Waroquier; Veronique Van Speybroeck
Journal:  Chem Mater       Date:  2016-07-25       Impact factor: 9.811

3.  Efficient Construction of Free Energy Profiles of Breathing Metal-Organic Frameworks Using Advanced Molecular Dynamics Simulations.

Authors:  Ruben Demuynck; Sven M J Rogge; Louis Vanduyfhuys; Jelle Wieme; Michel Waroquier; Veronique Van Speybroeck
Journal:  J Chem Theory Comput       Date:  2017-12-01       Impact factor: 6.006

4.  Gel-based morphological design of zirconium metal-organic frameworks.

Authors:  Bart Bueken; Niels Van Velthoven; Tom Willhammar; Timothée Stassin; Ivo Stassen; David A Keen; Gino V Baron; Joeri F M Denayer; Rob Ameloot; Sara Bals; Dirk De Vos; Thomas D Bennett
Journal:  Chem Sci       Date:  2017-03-23       Impact factor: 9.825

5.  Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering.

Authors:  Arthur De Vos; Kevin Hendrickx; Pascal Van Der Voort; Veronique Van Speybroeck; Kurt Lejaeghere
Journal:  Chem Mater       Date:  2017-03-10       Impact factor: 9.811

6.  Frustrated flexibility in metal-organic frameworks.

Authors:  Roman Pallach; Julian Keupp; Kai Terlinden; Louis Frentzel-Beyme; Marvin Kloß; Andrea Machalica; Julia Kotschy; Suresh K Vasa; Philip A Chater; Christian Sternemann; Michael T Wharmby; Rasmus Linser; Rochus Schmid; Sebastian Henke
Journal:  Nat Commun       Date:  2021-07-02       Impact factor: 14.919

7.  Transition Metal Coordination Polymers with Trans-1,4-Cyclohexanedicarboxylate: Acidity-Controlled Synthesis, Structures and Properties.

Authors:  Pavel A Demakov; Artem S Bogomyakov; Artem S Urlukov; Aleksandra Yu Andreeva; Denis G Samsonenko; Danil N Dybtsev; Vladimir P Fedin
Journal:  Materials (Basel)       Date:  2020-01-19       Impact factor: 3.623
  7 in total

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