Literature DB >> 26862591

Determining the structural stability of UiO-67 with respect to time: a solid-state NMR investigation.

M C Lawrence1, C Schneider2, M J Katz1.   

Abstract

The stability of UiO-67 has been questioned for some time. We have used solid-state NMR to investigate the temporal stability of this MOF. Proper activation is necessary to achieve optimal surface area. However, even with proper activation, the long-term (30+ days) fate of UiO-67 is hydrolysis of the linker-metal bonds and, ultimately, pore collapse.

Entities:  

Year:  2016        PMID： 26862591     DOI： 10.1039/c5cc09919f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Catalytic conversion of glucose to 5-hydroxymethylfurfural using zirconium-containing metal-organic frameworks using microwave heating.

Authors:  Jue Gong; Michael J Katz; Francesca M Kerton
Journal:  RSC Adv       Date:  2018-09-10       Impact factor: 4.036

2.  Understanding disorder and linker deficiency in porphyrinic zirconium-based metal-organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221.

Authors:  Charlotte Koschnick; Robert Stäglich; Tanja Scholz; Maxwell W Terban; Alberto von Mankowski; Gökcen Savasci; Florian Binder; Alexander Schökel; Martin Etter; Jürgen Nuss; Renée Siegel; Luzia S Germann; Christian Ochsenfeld; Robert E Dinnebier; Jürgen Senker; Bettina V Lotsch
Journal:  Nat Commun       Date:  2021-05-25       Impact factor: 14.919

3.  Molecular identification and quantification of defect sites in metal-organic frameworks with NMR probe molecules.

Authors:  Jinglin Yin; Zhengzhong Kang; Yao Fu; Weicheng Cao; Yiran Wang; Hanxi Guan; Yu Yin; Binbin Chen; Xianfeng Yi; Wei Chen; Wei Shao; Yihan Zhu; Anmin Zheng; Qi Wang; Xueqian Kong
Journal:  Nat Commun       Date:  2022-08-30       Impact factor: 17.694
  3 in total

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