| Literature DB >> 26845644 |
M E Casco1, Y Q Cheng2, L L Daemen2, D Fairen-Jimenez3, E V Ramos-Fernández1, A J Ramirez-Cuesta2, J Silvestre-Albero1.
Abstract
The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.Entities:
Year: 2016 PMID： 26845644 DOI： 10.1039/c5cc10222g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222