Literature DB >> 26845633

Hypervalent Iodine as a Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl Ketones.

Dipali A Chaudhari1, Rodney A Fernandes1.   

Abstract

A mimic of the Wacker process for C═O bond formation in terminal olefins can be initiated by a combination of the Pd(II) and hypervalent iodine reagent, Dess-Martin periodinane to generate methyl ketones. This operationally simple and scalable method offers Markovnikov selectivity, has good functional group compatibility, and is mild and high yielding.

Entities:  

Year:  2016        PMID： 26845633     DOI： 10.1021/acs.joc.6b00137

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  5 in total

1.  Regiocontrolled Wacker Oxidation of Cinnamyl Azides.

Authors:  Angela S Carlson; Cristian Calcanas; Ryan M Brunner; Joseph J Topczewski
Journal:  Org Lett       Date:  2018-03-02       Impact factor: 6.005

2.  Iron-Catalyzed Wacker-type Oxidation of Olefins at Room Temperature with 1,3-Diketones or Neocuproine as Ligands*.

Authors:  Florian Puls; Philipp Linke; Olga Kataeva; Hans-Joachim Knölker
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-14       Impact factor: 15.336

3.  Balancing Bulkiness in Gold(I) Phosphino-triazole Catalysis.

Authors:  Yiming Zhao; Matthew G Wakeling; Fernanda Meloni; Tze Jing Sum; Huy van Nguyen; Benjamin R Buckley; Paul W Davies; John S Fossey
Journal:  European J Org Chem       Date:  2019-07-30

Review 4.  Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents.

Authors:  Samata E Shetgaonkar; Ritu Mamgain; Kotaro Kikushima; Toshifumi Dohi; Fateh V Singh
Journal:  Molecules       Date:  2022-06-17       Impact factor: 4.927

5.  Valorization of cigarette butts for synthesis of levulinic acid as top value-added chemicals.

Authors:  Amelita G Laurenza; Onofrio Losito; Michele Casiello; Caterina Fusco; Angelo Nacci; Vincenzo Pantone; Lucia D'Accolti
Journal:  Sci Rep       Date:  2021-08-04       Impact factor: 4.379
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.