| Literature DB >> 26836947 |
Yong Wang1, Zhongle Li1, Liangbo Lv1, Zhixiang Xie1.
Abstract
A highly stereocontrolled construction of the C-5-epi ABCDE-ring system of rubriflordilactone B has been developed. The present synthesis features a convergent strategy to construct the C-5-epi AB-ring utilizing Mukaiyama-Michael reaction and forge the CDE ring in one step using intramolecular [2 + 2 + 2] cycloaddition of triynes.Entities:
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Year: 2016 PMID: 26836947 DOI: 10.1021/acs.orglett.6b00057
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005