Literature DB >> 26836340

The [B3(NN)3](+) and [B3(CO)3](+) Complexes Featuring the Smallest π-Aromatic Species B3(+).

Jiaye Jin1, Guanjun Wang1, Mingfei Zhou2, Diego M Andrada3, Markus Hermann3, Gernot Frenking4.   

Abstract

We report the spectroscopic identification of the [B3 (NN)3](+) and [B3 (CO)3](+) complexes, which feature the smallest π-aromatic system B3 (+). A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3 L2 ](+) σ-donation.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords:  aromaticity; bonding analysis; coordination chemistry; photodissociation; physical chemistry

Year:  2016        PMID： 26836340     DOI： 10.1002/anie.201509826

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide.

Authors:  Guohai Deng; Sudip Pan; Guanjun Wang; Lili Zhao; Mingfei Zhou; Gernot Frenking
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-13       Impact factor: 15.336

2.  Side-On Bonded Beryllium Dinitrogen Complexes.

Authors:  Guohai Deng; Sudip Pan; Guanjun Wang; Lili Zhao; Mingfei Zhou; Gernot Frenking
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-14       Impact factor: 15.336

3.  A Neutral Three-Membered 2π Aromatic Disilaborirane and the Unique Conversion into a Four-Membered BSi2 N-Ring.

Authors:  Samir Kumar Sarkar; Rinkumoni Chaliha; Mujahuddin M Siddiqui; Samya Banerjee; Annika Münch; Regine Herbst-Irmer; Dietmar Stalke; Eluvathingal D Jemmis; Herbert W Roesky
Journal:  Angew Chem Int Ed Engl       Date:  2020-10-12       Impact factor: 15.336
  3 in total

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