Literature DB >> 26809210

Homoleptic octahedral coordination of CH3CN to Mg(2+) in the Mg[N(SO2CF3)2]2-CH3CN system.

Gleb Veryasov1, Kazuhiko Matsumoto, Rika Hagiwara.   

Abstract

X-ray diffraction and Raman spectroscopic measurements revealed a homoleptic octahedral coordination of CH3CN to Mg(2+) in the [Mg(CH3CN)6][TFSA]2 (TFSA = bis(trifluoromethylsulfonyl)imide) crystal structure and in Mg[TFSA]2/CH3CN electrolytes.

Entities:  

Year:  2016        PMID： 26809210     DOI： 10.1039/c5dt04821d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  1 in total

1.  Super Mg2+ Conductivity around 10-3 S cm-1 Observed in a Porous Metal-Organic Framework.

Authors:  Yuto Yoshida; Teppei Yamada; Yuan Jing; Takashi Toyao; Ken-Ichi Shimizu; Masaaki Sadakiyo
Journal:  J Am Chem Soc       Date:  2022-05-04       Impact factor: 16.383
  1 in total

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