Literature DB >> 26800518

Porosity in metal-organic framework glasses.

A W Thornton1, K E Jelfs2, K Konstas1, C M Doherty1, A J Hill1, A K Cheetham3, T D Bennett3.   

Abstract

The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses.

Entities:  

Year:  2016        PMID： 26800518     DOI： 10.1039/c5cc10072k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Accurate Characterization of the Pore Volume in Microporous Crystalline Materials.

Authors:  Daniele Ongari; Peter G Boyd; Senja Barthel; Matthew Witman; Maciej Haranczyk; Berend Smit
Journal:  Langmuir       Date:  2017-07-10       Impact factor: 3.882

Review 2.  MOF the beaten track: unusual structures and uncommon applications of metal-organic frameworks.

Authors:  Alexander J Tansell; Corey L Jones; Timothy L Easun
Journal:  Chem Cent J       Date:  2017-10-11       Impact factor: 4.215

3.  Materials Genome in Action: Identifying the Performance Limits of Physical Hydrogen Storage.

Authors:  Aaron W Thornton; Cory M Simon; Jihan Kim; Ohmin Kwon; Kathryn S Deeg; Kristina Konstas; Steven J Pas; Matthew R Hill; David A Winkler; Maciej Haranczyk; Berend Smit
Journal:  Chem Mater       Date:  2017-03-08       Impact factor: 9.811

4.  A metal-organic framework with ultrahigh glass-forming ability.

Authors:  Ang Qiao; Thomas D Bennett; Haizheng Tao; Andraž Krajnc; Gregor Mali; Cara M Doherty; Aaron W Thornton; John C Mauro; G Neville Greaves; Yuanzheng Yue
Journal:  Sci Adv       Date:  2018-03-09       Impact factor: 14.136

Review 5.  Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber.

Authors:  Cristina Mottillo; Tomislav Friščić
Journal:  Molecules       Date:  2017-01-17       Impact factor: 4.411

6.  Mixed hierarchical local structure in a disordered metal-organic framework.

Authors:  Adam F Sapnik; Irene Bechis; Sean M Collins; Duncan N Johnstone; Giorgio Divitini; Andrew J Smith; Philip A Chater; Matthew A Addicoat; Timothy Johnson; David A Keen; Kim E Jelfs; Thomas D Bennett
Journal:  Nat Commun       Date:  2021-04-06       Impact factor: 14.919

7.  Metal-organic framework glasses with permanent accessible porosity.

Authors:  Chao Zhou; Louis Longley; Andraž Krajnc; Glen J Smales; Ang Qiao; Ilknur Erucar; Cara M Doherty; Aaron W Thornton; Anita J Hill; Christopher W Ashling; Omid T Qazvini; Seok J Lee; Philip A Chater; Nicholas J Terrill; Andrew J Smith; Yuanzheng Yue; Gregor Mali; David A Keen; Shane G Telfer; Thomas D Bennett
Journal:  Nat Commun       Date:  2018-11-28       Impact factor: 14.919
  7 in total

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