Literature DB >> 26768824

Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base.

Holger Braunschweig1, Rian D Dewhurst2, Leanne Pentecost3, Krzysztof Radacki2, Alfredo Vargas3, Qing Ye2.   

Abstract

An electron-rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The hard Lewis acid AlCl3 binds through a nitrogen atom of the Lewis base, while softer Lewis acids GaX3 (Cl, Br, I) bind at the boron atom. The latter are the first noncluster Lewis adducts between a boron-centered Lewis base and a main-group Lewis acid.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lewis adducts; alanes; boron; dative bonding; gallanes

Year:  2015        PMID： 26768824     DOI： 10.1002/anie.201509289

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Sterically Unprotected Nucleophilic Boron Cluster Reagents.

Authors:  Xin Mu; Jonathan C Axtell; Nicholas A Bernier; Kent O Kirlikovali; Dahee Jung; Alexander Umanzor; Kevin Qian; Xiangyang Chen; Katherine L Bay; Monica Kirollos; Arnold L Rheingold; K N Houk; Alexander M Spokoyny
Journal:  Chem       Date:  2019-08-22       Impact factor: 22.804

2.  Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene.

Authors:  Merle Arrowsmith; Sara Endres; Myron Heinz; Vincent Nestler; Max C Holthausen; Holger Braunschweig
Journal:  Chemistry       Date:  2021-11-11       Impact factor: 5.020

3.  Ambiphilic boron in 1,4,2,5-diazadiborinine.

Authors:  Baolin Wang; Yongxin Li; Rakesh Ganguly; Hajime Hirao; Rei Kinjo
Journal:  Nat Commun       Date:  2016-06-09       Impact factor: 14.919

4.  Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.

Authors:  Anne-Frédérique Pécharman; Annie L Colebatch; Michael S Hill; Claire L McMullin; Mary F Mahon; Catherine Weetman
Journal:  Nat Commun       Date:  2017-04-07       Impact factor: 14.919

5.  Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.

Authors:  Johannes Landmann; Philipp T Hennig; Nikolai V Ignat'ev; Maik Finze
Journal:  Chem Sci       Date:  2017-06-26       Impact factor: 9.825

Review 6.  Boron: Its Role in Energy-Related Processes and Applications.

Authors:  Zhenguo Huang; Suning Wang; Rian D Dewhurst; Nikolai V Ignat'ev; Maik Finze; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-06       Impact factor: 15.336
  6 in total

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