Literature DB >> 26758474

White phosphorus activation by a Th(III) complex.

Alasdair Formanuik1, Fabrizio Ortu, Reece Beekmeyer, Andrew Kerridge, Ralph W Adams, David P Mills.   

Abstract

[Th(Cp'')3] (Cp'' = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp'')3}2(μ-η(1):η(1)-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.

Entities:  

Year:  2016        PMID： 26758474     DOI： 10.1039/c5dt04528b

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-03-09       Impact factor: 14.919

Review 2.  Actinide Organometallic Complexes with π-Ligands.

Authors:  Olaf Walter
Journal:  Chemistry       Date:  2018-12-18       Impact factor: 5.236

3.  Thorium-phosphorus triamidoamine complexes containing Th-P single- and multiple-bond interactions.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2016-09-29       Impact factor: 14.919

4.  Concomitant Carboxylate and Oxalate Formation From the Activation of CO2 by a Thorium(III) Complex.

Authors:  Alasdair Formanuik; Fabrizio Ortu; Christopher J Inman; Andrew Kerridge; Ludovic Castro; Laurent Maron; David P Mills
Journal:  Chemistry       Date:  2016-10-27       Impact factor: 5.236
  4 in total

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