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Literature DB >> 26758387

Upgrading ethanol to 1-butanol with a homogeneous air-stable ruthenium catalyst.

Kuei-Nin T Tseng¹, Steve Lin¹, Jeff W Kampf¹, Nathaniel K Szymczak¹.

Abstract

An amide-derived N,N,N-Ru(ii) complex catalyzes the conversion of EtOH to 1-BuOH with high activity. Conversion to alcohol upgraded products exceeds 250 turnovers per hour (>50% conversion) with 0.1 mol% catalyst loading. In addition to high activity for ethanol upgrading, catalytic reactions can be set up under ambient conditions with no loss in activity.

Entities: Chemical

Year: 2016 PMID： 26758387 DOI： 10.1039/c5cc09913g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Stereoretentive Deuteration of α-Chiral Amines with D₂O.

Authors: Lillian V A Hale; Nathaniel K Szymczak
Journal: J Am Chem Soc Date: 2016-10-06 Impact factor: 15.419

Review 2. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors: Amit Kumar; Prosenjit Daw; David Milstein
Journal: Chem Rev Date: 2021-11-02 Impact factor: 60.622

Review 3. Borrowing Hydrogen for Organic Synthesis.

Authors: Benjamin G Reed-Berendt; Daniel E Latham; Mubarak B Dambatta; Louis C Morrill
Journal: ACS Cent Sci Date: 2021-03-25 Impact factor: 14.553

4. Manganese Diphosphine and Phosphinoamine Complexes Are Effective Catalysts for the Production of Biofuel Alcohols via the Guerbet Reaction.

Authors: Ashley M King; Hazel A Sparkes; Richard L Wingad; Duncan F Wass
Journal: Organometallics Date: 2020-10-26 Impact factor: 3.876

Upgrading ethanol to 1-butanol with a homogeneous air-stable ruthenium catalyst.

1. Stereoretentive Deuteration of α-Chiral Amines with D₂O.

Review 2. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Review 3. Borrowing Hydrogen for Organic Synthesis.

4. Manganese Diphosphine and Phosphinoamine Complexes Are Effective Catalysts for the Production of Biofuel Alcohols via the Guerbet Reaction.

Review 5. Renewable Butanol Production via Catalytic Routes.

6. Efficient conversion of ethanol to 1-butanol and C₅-C₉ alcohols over calcium carbide.

Review 7. Bringing Homogeneous Iron Catalysts on the Heterogeneous Side: Solutions for Immobilization.

Upgrading ethanol to 1-butanol with a homogeneous air-stable ruthenium catalyst.

1. Stereoretentive Deuteration of α-Chiral Amines with D2O.

Review 2. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Review 3. Borrowing Hydrogen for Organic Synthesis.

4. Manganese Diphosphine and Phosphinoamine Complexes Are Effective Catalysts for the Production of Biofuel Alcohols via the Guerbet Reaction.

Review 5. Renewable Butanol Production via Catalytic Routes.

6. Efficient conversion of ethanol to 1-butanol and C5-C9 alcohols over calcium carbide.

Review 7. Bringing Homogeneous Iron Catalysts on the Heterogeneous Side: Solutions for Immobilization.

1. Stereoretentive Deuteration of α-Chiral Amines with D₂O.

6. Efficient conversion of ethanol to 1-butanol and C₅-C₉ alcohols over calcium carbide.