| Literature DB >> 26753188 |
Sergei Krupski1, Gerald Kehr1, Constantin G Daniliuc1, Gerhard Erker1.
Abstract
Reaction of the -CH2OSiMe3 substituted allyldimesitylphosphane 5 with HB(C6F5)2 resulted in a hydroboration/(C6F5)2BOSiMe3 elimination sequence to give the phosphinomethyl substituted cyclopropane derivative , probably via a phosphiranium type intermediate. Addition of B(C6F5)3 to compound gave the stable phosphiranium/borate zwitterion that was isolated and characterized by X-ray diffraction.Entities:
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Year: 2016 PMID： 26753188 DOI： 10.1039/c5cc09585a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222