| Literature DB >> 26746881 |
Yinuo Wu1, Lei Sun1, Yunyun Chen1, Qian Zhou1, Jia-Wu Huang1, Hui Miao1, Hai-Bin Luo1.
Abstract
A palladium-catalyzed oxidative C-H bond decarboxylative acylation of N-nitrosoanilines using α-oxocarboxylic acid as the acyl source is described. The catalyst Pd(OAc)2 and oxidant (NH4)2S2O8 enabled ortho-acylation of N-nitrosoanilines at room temperature, affording an array of N-nitroso-2-aminobenzophenones in moderate to excellent yields.Entities:
Year: 2016 PMID： 26746881 DOI： 10.1021/acs.joc.5b02535
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354