Cross-Linked Chitosan as an Efficient Binder for Si Anode of Li-ion Batteries.

We investigate the use of chitosan (CS) as a new cross-linkable and water-soluble binder for the Si anode of Li-ion batteries. In contrast to the traditional binder utilizing a hydrogen bond and/or van der Waals force-linked anode electrodes, CS can easily form a 3D network to limit the movement of Si particles through the cross-linking between the amino groups of CS and the dialdehyde of glutaraldehyde (GA). Chemical, mechanical, and morphological analyses are conducted by Fourier transform infrared spectroscopy, tensile testing, and scanning electron microscopy. The cross-linked Si/CS-GA anode exhibits an initial discharge capacity of 2782 mAh g(-1) with a high initial Coulombic efficiency of 89% and maintained a capacity of 1969 mAh g(-1) at the current density of 500 mA g(-1) over 100 cycles.