| Literature DB >> 26743893 |
Lingbing Kong1, Rakesh Ganguly2, Yongxin Li2, Rei Kinjo3.
Abstract
Oxidative addition of the C-O bond in L2 PhB: (L=oxazol-2-ylidene) to an AlI center induced ring expansion of an oxazol-2-ylidene ring, affording a unique organoboron species formally involving either an Al, N, O mixed heterocyclic carbene or anionic (amino)(boryl)carbene fragment.Entities:
Keywords: aluminum; carbenes; density functional calculations; oxidative addition; ring expansion
Year: 2016 PMID： 26743893 DOI： 10.1002/chem.201504537
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236