Literature DB >> 26736069

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow.

Quentin Lefebvre1, Norbert Hoffmann, Magnus Rueping.   

Abstract

Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

Entities:  

Year:  2016        PMID： 26736069     DOI： 10.1039/c5cc09881e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

Review 2.  Recent Developments in the Photochemical Synthesis of Functionalized Imidazopyridines.

Authors:  Christine Tran; Abdallah Hamze
Journal:  Molecules       Date:  2022-05-27       Impact factor: 4.927

3.  Laser-Initiated Radical Trifluoromethylation of Peptides and Proteins: Application to Mass-Spectrometry-Based Protein Footprinting.

Authors:  Ming Cheng; Bojie Zhang; Weidong Cui; Michael L Gross
Journal:  Angew Chem Int Ed Engl       Date:  2017-10-05       Impact factor: 15.336

4.  CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na.

Authors:  Hélène Guyon; Hélène Chachignon; Dominique Cahard
Journal:  Beilstein J Org Chem       Date:  2017-12-19       Impact factor: 2.883

5.  Electrophotocatalytic Undirected C-H Trifluoromethylations of (Het)Arenes.

Authors:  Youai Qiu; Alexej Scheremetjew; Lars H Finger; Lutz Ackermann
Journal:  Chemistry       Date:  2020-02-19       Impact factor: 5.236

6.  One Amine-3 Tasks: Reductive Coupling of Imines with Olefins in Batch and Flow.

Authors:  Quentin Lefebvre; Riccardo Porta; Anthony Millet; Jiaqi Jia; Magnus Rueping
Journal:  Chemistry       Date:  2020-01-21       Impact factor: 5.236

7.  Photoredox-Catalyzed Ketyl-Olefin Coupling for the Synthesis of Substituted Chromanols.

Authors:  Eleonora Fava; Masaki Nakajima; Anh L P Nguyen; Magnus Rueping
Journal:  J Org Chem       Date:  2016-07-21       Impact factor: 4.354

8.  Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with water.

Authors:  Sadhan Jana; Ajay Verma; Rahul Kadu; Sangit Kumar
Journal:  Chem Sci       Date:  2017-07-10       Impact factor: 9.825

9.  Ruthenium-Catalyzed Site-Selective Trifluoromethylations and (Per)Fluoroalkylations of Anilines and Indoles.

Authors:  Yang Li; Helfried Neumann; Matthias Beller
Journal:  Chemistry       Date:  2020-05-12       Impact factor: 5.236
  9 in total

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