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Literature DB >> 26727613

Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System.

Abstract

The hydroalkylation of alkenes using alkyl iodides with Hantzsch ester as a hydrogen source occurred smoothly under a Pd/light system, in a novel, tin-free Giese reaction. A chemoselective reaction at C(sp(3))-I in the presence of a C(sp(2))-X (X = Br or I) bond was attained, which allowed for the stepwise functionalization of two types of C-X bonds in a one-pot procedure.

Entities: Chemical

Year: 2015 PMID： 26727613 DOI： 10.1021/acs.orglett.5b03238

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

2 in total

1. Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp³ )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.

Authors: Maxim Ratushnyy; Marvin Parasram; Yang Wang; Vladimir Gevorgyan
Journal: Angew Chem Int Ed Engl Date: 2018-02-06 Impact factor: 15.336

2. Photocatalytic Hydroalkylation of Aryl-Alkenes.

Authors: Cornelia S Buettner; Michael Schnürch; Katharina Bica-Schröder
Journal: J Org Chem Date: 2022-08-01 Impact factor: 4.198

2 in total

Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System.

1. Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.

2. Photocatalytic Hydroalkylation of Aryl-Alkenes.

1. Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp³ )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.