Literature DB >> 26726126

Cuprophilic interactions in highly luminescent dicopper(i)-NHC-picolyl complexes - fast phosphorescence or TADF?

Jörn Nitsch1, Frederick Lacemon2, Andreas Lorbach1, Antonius Eichhorn1, Federico Cisnetti2, Andreas Steffen1.   

Abstract

This case study on a series of monomeric, dimeric and polymeric Cu(I) chlorido NHC-picolyl complexes shows that cuprophilic interactions can ensure strong spin-orbit coupling for fast (reverse)intersystem-crossing T1 ↔ S1 and T1 → S0, and therefore can serve as a design motif for the construction of highly efficient Cu(I)-based TADF or T1 emitters.

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Year:  2016        PMID： 26726126     DOI： 10.1039/c5cc09659f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Optically Modulated and Optically Activated Delayed Fluorescent Proteins through Dark State Engineering.

Authors:  Baijie Peng; Ryan Dikdan; Shannon E Hill; Athéna C Patterson-Orazem; Raquel L Lieberman; Christoph J Fahrni; Robert M Dickson
Journal:  J Phys Chem B       Date:  2021-05-12       Impact factor: 3.466

2.  Thermally Activated Delayed Fluorescence in CuI Complexes Originating from Restricted Molecular Vibrations.

Authors:  Guangfu Li; Roberto S Nobuyasu; Baohua Zhang; Yun Geng; Bing Yao; Zhiyuan Xie; Dongxia Zhu; Guogang Shan; Weilong Che; Likai Yan; Zhongmin Su; Fernando B Dias; Martin R Bryce
Journal:  Chemistry       Date:  2017-08-10       Impact factor: 5.236

3.  Relevance of Orbital Interactions and Pauli Repulsion in the Metal-Metal Bond of Coinage Metals.

Authors:  Maria B Brands; Jörn Nitsch; Célia Fonseca Guerra
Journal:  Inorg Chem       Date:  2018-02-12       Impact factor: 5.165

4.  Solvent-driven structural topology involving energetically significant intra- and intermolecular chelate ring contacts and anticancer activities of Cu(ii) phenanthroline complexes involving benzoates: experimental and theoretical studies.

Authors:  Manjit K Bhattacharyya; Utpal Saha; Debajit Dutta; Amal Das; Akalesh K Verma; Antonio Frontera
Journal:  RSC Adv       Date:  2019-05-24       Impact factor: 4.036

5.  Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights.

Authors:  Miguel González-Lainez; Miguel Gallegos; Julen Munarriz; Ramón Azpiroz; Vincenzo Passarelli; M Victoria Jiménez; Jesús J Pérez-Torrente
Journal:  Organometallics       Date:  2022-07-15       Impact factor: 3.837
  5 in total

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