Literature DB >> 26718908

Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity.

Jason G Harrison1, Osvaldo Gutierrez1, Navendu Jana2, Tom G Driver2,3, Dean J Tantillo1.   

Abstract

Possible mechanisms for Rh-promoted indole formation from vinyl/azidoarenes were examined computationally, and a mechanism is proposed in which the Rh catalyst promotes generation of a nitrene but is not directly involved in cyclization.

Entities:  

Year:  2016        PMID： 26718908     DOI： 10.1021/jacs.5b11427

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  The synthesis of quinolines via denitrogenative palladium-catalyzed cascade reaction of o-aminocinnamonitriles with arylhydrazines.

Authors:  Jing Xie; Hang Huang; Tong Xu; Renhao Li; Jiuxi Chen; Xueting Ye
Journal:  RSC Adv       Date:  2020-03-03       Impact factor: 4.036

2.  Catalyst-Controlled Regiodivergence in Rearrangements of Indole-Based Onium Ylides.

Authors:  Vaishnavi N Nair; Volga Kojasoy; Croix J Laconsay; Wang Yeuk Kong; Dean J Tantillo; Uttam K Tambar
Journal:  J Am Chem Soc       Date:  2021-06-14       Impact factor: 16.383

3.  Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C-H insertion of donor/donor carbenes.

Authors:  Leslie A Nickerson; Benjamin D Bergstrom; Mingchun Gao; Yuan-Shin Shiue; Croix J Laconsay; Matthew R Culberson; Walker A Knauss; James C Fettinger; Dean J Tantillo; Jared T Shaw
Journal:  Chem Sci       Date:  2019-11-13       Impact factor: 9.825
  3 in total

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