SnS Thin Film Prepared by Pyrolytic Synthesis as an Efficient Counter Electrode in Quantum Dot Sensitized Solar Cells.

The SnS thin films were successfully prepared by pyrolysis procedure for the counter electrodes in quantum dot sensitized solar cells (QDSCs) using the methanol solution containing stannous chloride dihydrate (0.40 mol x L(-1)) and thiourea (0.40 mol x L(-1)) as precursor solution at 300 degrees C in the air atmosphere. The electrochemical catalytic activity of the SnS thin films prepared by pyrolytic synthesis for the redox couple of S(2-)/S(2-) was investigated by electrochemical impedance spectroscopy. The result revealed that the charge transfer resistance of the as-prepared SnS thin film with the dipping-heating cycles of 5 was 106.4 Ω and the corresponded QDSCs gave a short circuit photocurrent density of 8.69 mA x cm(-2), open circuit voltage of 0.42 V, and fill factor of 0.43, yielding the photoelectric conversion efficiency of 1.57%, under the illumination of simulated AM 1.5 sunlight (100 mWx cm(-2)).