Rheological Characterization of Liquid Polymers Containing Ceramic Nanopowders for Use in Thermoelectric Devices.

We have determined shear viscosities as a function of temperature for several liquid high temperature polymers (HTPs) as potential coatings for solid state thermoelectric generators (TEGs) as well as for TE coolers (TECs). To each HTP we added in turn several ceramic nanopowders: alumina, silica and multi-wall carbon nanotubes (MWCNTs). The shear rate applied range is from 0.0002 to 60 s(-1). The results are compared to those for neat HTPs. For a given HTP, we obtain for some nanopowders significant lowering of viscosity, or else a significant increase, or else a small effect only. Possible reasons for such differences in behavior are discussed in terms of the spatial structures of CNTs (random orientations at low temperatures), and the interactions between functional groups on HTPs and atoms in the nanoceramics.