Literature DB >> 26711532

Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond.

Laura Nunes Dos Santos Comprido1, Johannes E M N Klein2, Gerald Knizia3, Johannes Kästner4, A Stephen K Hashmi5,6.   

Abstract

We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  carbene; computational chemistry; gold; vinylidene

Year:  2016        PMID： 26711532     DOI： 10.1002/chem.201504511

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  7 in total

1.  Efficient Computation of Geometries for Gold Complexes.

Authors:  Isaac F Leach; Leonardo Belpassi; Paola Belanzoni; Remco W A Havenith; Johannes E M N Klein
Journal:  Chemphyschem       Date:  2021-05-28       Impact factor: 3.102

2.  Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes.

Authors:  Jiwei Wang; Xiaoming Cao; Shichang Lv; Caiyun Zhang; Sheng Xu; Min Shi; Jun Zhang
Journal:  Nat Commun       Date:  2017-03-06       Impact factor: 14.919

Review 3.  σ-Noninnocence: Masked Phenyl-Cation Transfer at Formal NiIV.

Authors:  Jelte S Steen; Gerald Knizia; Johannes E M N Klein
Journal:  Angew Chem Int Ed Engl       Date:  2019-07-15       Impact factor: 15.336

4.  Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects.

Authors:  Diego Sorbelli; Laura Nunes Dos Santos Comprido; Gerald Knizia; A Stephen K Hashmi; Leonardo Belpassi; Paola Belanzoni; Johannes E M N Klein
Journal:  Chemphyschem       Date:  2019-06-13       Impact factor: 3.102

5.  DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes.

Authors:  Nasir A Rajabi; Claire L McMullin
Journal:  RSC Adv       Date:  2021-03-23       Impact factor: 3.361

6.  Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity.

Authors:  Hongming Jin; Wen-Yan Tong; Jing Zhang; Matthias Rudolph; Frank Rominger; Xu Shen; Shuanglin Qu; A Stephen K Hashmi
Journal:  Nat Commun       Date:  2022-03-30       Impact factor: 14.919

7.  The Pentagonal-Pyramidal Hexamethylbenzene Dication: Many Shades of Coordination Chemistry at Carbon.

Authors:  Johannes E M N Klein; Remco W A Havenith; Gerald Knizia
Journal:  Chemistry       Date:  2018-03-09       Impact factor: 5.236
  7 in total

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