| Literature DB >> 26709440 |
Cecilia Tortoreto1, Thierry Achard1, Léo Egger1, Laure Guénée2, Jérôme Lacour1.
Abstract
Reactions of α-diazo-β-ketoesters with cyclic ketones, lactones, and carbonates are reported. Thanks to the combined use of salt [CpRu(CH3CN)3][BArF] and 1,10-phenanthroline as catalyst for the diazo decomposition, effective and practical syntheses of spiro bicyclic ketals, orthoesters, and orthocarbonates are afforded.Entities:
Year: 2015 PMID： 26709440 DOI： 10.1021/acs.orglett.5b03380
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005