Literature DB >> 26699399

Threading a Ring or Tube onto a Rod: An Entropically Rare Event.

Edith M Sevick1, David R M Williams1.   

Abstract

We calculate the entropy lost when a circular ring or a circular cylinder or tube is threaded onto a long rod in terms of the geometrical parameters, namely rod length and radius, the threaded ring radius, or the radius and length of a threaded tube. These formulas, constructed from a partition function, allow calculation of the fraction of rings/tubes threaded spontaneously onto rods. In all cases of practical interest, this fraction is very small and can be well represented by simple power laws depending strongly upon the geometrical parameters.

Entities:  

Keywords:  Threading; nanotubes; orientational entropy; polymer translocation; rotaxanes

Year:  2015        PMID: 26699399     DOI: 10.1021/acs.nanolett.5b04440

Source DB:  PubMed          Journal:  Nano Lett        ISSN: 1530-6984            Impact factor:   11.189


  2 in total

1.  DNA Origami Rotaxanes: Tailored Synthesis and Controlled Structure Switching.

Authors:  John T Powell; Benjamin O Akhuetie-Oni; Zhao Zhang; Chenxiang Lin
Journal:  Angew Chem Int Ed Engl       Date:  2016-08-16       Impact factor: 15.336

Review 2.  Individual-Molecule Perspective Analysis of Chemical Reaction Networks: The Case of a Light-Driven Supramolecular Pump.

Authors:  Andrea Sabatino; Emanuele Penocchio; Giulio Ragazzon; Alberto Credi; Diego Frezzato
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-23       Impact factor: 15.336

  2 in total

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