| Literature DB >> 26692111 |
Mayra Delgado, Joshua M Ziegler, Takele Seda, Lev N Zakharov1, John D Gilbertson.
Abstract
A series of pyridinediimine (PDI) iron complexes that contain a pendant 15-crown-5 located in the secondary coordination sphere were synthesized and characterized. The complex Fe((15c5)PDI)(CO)2 (2) was shown in both the solid state and solution to encapsulate redox-inactive metal ions. Modest shifts in the reduction potential of the metal-ligand scaffold were observed upon encapsulation of either Na(+) or Li(+).Entities:
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Year: 2015 PMID： 26692111 DOI： 10.1021/acs.inorgchem.5b02544
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165