Literature DB >> 26673868

NHC-based pincer ligands: carbenes with a bite.

Rhiann E Andrew1, Lucero González-Sebastián1, Adrian B Chaplin1.   

Abstract

In this frontier article we overview the emergence and scope of NHC-based CCC and CNC pincer systems, i.e. complexes containing mer-tridentate ligands bearing two NHC donor groups, comment on their effectiveness in applications, and highlight areas for future development and exploitation.

Entities:  

Year:  2016        PMID： 26673868     DOI： 10.1039/c5dt04429d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  11 in total

1.  Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles.

Authors:  Rhiann E Andrew; Caroline M Storey; Adrian B Chaplin
Journal:  Dalton Trans       Date:  2016-05-09       Impact factor: 4.390

Review 2.  Recent advances in phosphorescent platinum complexes for organic light-emitting diodes.

Authors:  Cristina Cebrián; Matteo Mauro
Journal:  Beilstein J Org Chem       Date:  2018-06-18       Impact factor: 2.883

3.  Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen.

Authors:  Matthew R Gyton; Baptiste Leforestier; Adrian B Chaplin
Journal:  Organometallics       Date:  2018-10-09       Impact factor: 3.876

4.  Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study.

Authors:  Gemma L Parker; Samantha Lau; Baptiste Leforestier; Adrian B Chaplin
Journal:  Eur J Inorg Chem       Date:  2019-08-23       Impact factor: 2.524

Review 5.  Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.

Authors:  Sem Raj Tamang; Michael Findlater
Journal:  Molecules       Date:  2019-09-03       Impact factor: 4.411

6.  N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.

Authors:  Sunit Hazra; Yoichi Hoshimoto; Sensuke Ogoshi
Journal:  Chemistry       Date:  2017-10-04       Impact factor: 5.236

7.  Synergic Deprotonation Generates Alkali-Metal Salts of Tethered Fluorenide-NHC Ligands Co-Complexed to Alkali-Metal Amides.

Authors:  Kieren J Evans; Stephen M Mansell
Journal:  Chemistry       Date:  2019-02-19       Impact factor: 5.236

8.  A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes.

Authors:  Caroline M Storey; Audrius Kalpokas; Matthew R Gyton; Tobias Krämer; Adrian B Chaplin
Journal:  Chem Sci       Date:  2020-01-22       Impact factor: 9.825

9.  Efficient and Practical Transfer Hydrogenation of Ketones Catalyzed by a Simple Bidentate Mn-NHC Complex.

Authors:  Robbert van Putten; Joeri Benschop; Vincent J de Munck; Manuela Weber; Christian Müller; Georgy A Filonenko; Evgeny A Pidko
Journal:  ChemCatChem       Date:  2019-07-08       Impact factor: 5.686

10.  Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity.

Authors:  Caroline M Storey; Matthew R Gyton; Rhiann E Andrew; Adrian B Chaplin
Journal:  Chemistry       Date:  2020-10-12       Impact factor: 5.236
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