| Literature DB >> 26673685 |
Heng Zhang1, Rong-Bin Hu1, Na Liu1, Shi-Xia Li1, Shang-Dong Yang1,2.
Abstract
The first Pd-catalyzed allylic dearomatization of substituted indoles triggered by C-H bond activation is reported. The presence of a catalytic amount of 2,5-DMBQ is proven to be a key factor for the high yield. This one-pot tandem allylic C-H activation/dearomatization sequence provides a straightforward access to 3,3-disubstituted indolines.Entities:
Year: 2015 PMID： 26673685 DOI： 10.1021/acs.orglett.5b03053
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005