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Literature DB >> 26658383

Recent advances in the chemistry of organic thiocyanates.

Thomas Castanheiro¹, Jean Suffert, Morgan Donnard, Mihaela Gulea.

Abstract

Organic thiocyanates are important synthetic intermediates to access valuable sulfur-containing compounds. In this review the different methods for their preparation and their synthetic applications will be presented. The literature of the last 15 years will be covered, highlighting selected recent advances in the chemistry of this class of compounds. We hope to offer chemists the tools to have a good grasp of this singular functionality and open the door to further progress in this chemistry.

Entities: Chemical

Mesh：

Substances：
Thiocyanates

Year: 2015 PMID： 26658383 DOI： 10.1039/c5cs00532a

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

14 in total

1. Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation.

Authors: Alexander Lipp; Shorouk O Badir; Ryan Dykstra; Osvaldo Gutierrez; Gary A Molander
Journal: Adv Synth Catal Date: 2021-05-19 Impact factor: 5.981

2. Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols.

Authors: Chandra Kant Maurya; Avik Mazumder; Pradeep Kumar Gupta
Journal: Beilstein J Org Chem Date: 2017-06-20 Impact factor: 2.883

3. Conformation-specific detection of calmodulin binding using the unnatural amino acid p-azido-phenylalanine (AzF) as an IR-sensor.

Authors: Anne Creon; Inokentijs Josts; Stephan Niebling; Nils Huse; Henning Tidow
Journal: Struct Dyn Date: 2018-11-07 Impact factor: 2.920

4. Ammonium [¹¹C]thiocyanate: revised preparation and reactivity studies of a versatile nucleophile for carbon-11 radiolabelling.

Authors: Tom Haywood; Sara Cesarec; Steven Kealey; Christophe Plisson; Philip W Miller
Journal: Medchemcomm Date: 2018-07-02 Impact factor: 3.597

5. Development of a New Bioprocess for Clean Diosgenin Production through Submerged Fermentation of an Endophytic Fungus.

Authors: Wancang Liu; Haibo Xiang; Tao Zhang; Xu Pang; Jing Su; Hongyu Liu; Baiping Ma; Liyan Yu
Journal: ACS Omega Date: 2021-03-31

Review 6. Recent advances in photochemical and electrochemically induced thiocyanation: a greener approach for SCN-containing compound formation.

Authors: Pran Gopal Karmaker; Md Asraful Alam; Feng Huo
Journal: RSC Adv Date: 2022-02-22 Impact factor: 3.361

Recent advances in the chemistry of organic thiocyanates.

1. Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation.

2. Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols.

3. Conformation-specific detection of calmodulin binding using the unnatural amino acid p-azido-phenylalanine (AzF) as an IR-sensor.

4. Ammonium [¹¹C]thiocyanate: revised preparation and reactivity studies of a versatile nucleophile for carbon-11 radiolabelling.

5. Development of a New Bioprocess for Clean Diosgenin Production through Submerged Fermentation of an Endophytic Fungus.

Review 6. Recent advances in photochemical and electrochemically induced thiocyanation: a greener approach for SCN-containing compound formation.

7. Gold Leaching from an Oxide Ore Using Thiocyanate as a Lixiviant: Process Optimization and Kinetics.

8. Ag/Pyridine Co-Mediated Oxidative Arylthiocyanation of Activated Alkenes.

9. Pd-Catalyzed Directed Thiocyanation Reaction by C-H Bond Activation.

10. Straightforward Access to Thiocyanates via Dealkylative Cyanation of Sulfoxides.