Literature DB >> 26651277

Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation.

Zhengbiao He1, Ping Tan1, Jinbo Hu1.   

Abstract

An efficient copper-catalyzed trifluoromethylation of polysubstituted alkenes assisted by decarboxylation of β,γ-unsaturated carboxylic acids has been achieved. The reaction provides a general method to construct allylic and vinylic CF3-substituted compounds under mild conditions.

Entities:  

Year:  2015        PMID： 26651277     DOI： 10.1021/acs.orglett.5b03290

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Hydroamination of Dihapto-Coordinated Benzene and Diene Complexes of Tungsten: Fundamental Studies and the Synthesis of γ-Lycorane.

Authors:  Katy B Wilson; Hannah S Nedzbala; Spenser R Simpson; Megan N Ericson; Karl S Westendorff; Mahendra D Chordia; Diane A Dickie; W Dean Harman
Journal:  Helv Chim Acta       Date:  2021-08-10       Impact factor: 2.164

2.  Interrupting the Barton-McCombie Reaction: Aqueous Deoxygenative Trifluoromethylation of O-Alkyl Thiocarbonates.

Authors:  Zhi-Yun Liu; Silas P Cook
Journal:  Org Lett       Date:  2021-01-14       Impact factor: 6.072

3.  Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.

Authors:  Weiming Yuan; Lars Eriksson; Kálmán J Szabó
Journal:  Angew Chem Int Ed Engl       Date:  2016-05-24       Impact factor: 15.336

4.  Ruthenium-Catalyzed Site-Selective Trifluoromethylations and (Per)Fluoroalkylations of Anilines and Indoles.

Authors:  Yang Li; Helfried Neumann; Matthias Beller
Journal:  Chemistry       Date:  2020-05-12       Impact factor: 5.236
  4 in total

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