| Literature DB >> 26630076 |
B Adinarayana1, Ajesh P Thomas1, Prerna Yadav1, Arun Kumar1, A Srinivasan2.
Abstract
In the corrole homologue, 6,11,16-triarylbipyricorrole, the bipyrrole unit is replaced by a 2,2'-bipyridine unit. This modification effectively alters the corrole N4 coordination sphere from the trianionic [(NH)3 N] to the monoanionic [N3NH] state. The newly formed monoanionic core stabilizes Zn(II) ions with enhanced emission properties. The enhanced emission was further utilized for metal ion sensing studies and exploited for the selective detection of Zn(II) ions.Entities:
Keywords: bipyridyl units; corroles; monoanionic; nonaromaticity; sensing studies
Year: 2015 PMID： 26630076 DOI： 10.1002/anie.201508829
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336