Literature DB >> 26624568

Nickel-Catalyzed Formal Homocoupling of Methoxyarenes for the Synthesis of Symmetrical Biaryls via C-O Bond Cleavage.

Keisuke Nakamura1, Mamoru Tobisu1,2, Naoto Chatani1.   

Abstract

A new method has been developed for the nickel-catalyzed homocoupling of methoxyarenes via C-O bond cleavage using a diboron reagent. The use of 1,3-dicyclohexylimidazol-2-ylidene as a ligand was found to be critical to the success of the reaction. This new method allows the synthesis of a wide range of biaryl compounds.

Entities:  

Year:  2015        PMID： 26624568     DOI： 10.1021/acs.orglett.5b03151

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Alkynoates as Versatile and Powerful Chemical Tools for the Rapid Assembly of Diverse Heterocycles under Transition-Metal Catalysis: Recent Developments and Challenges.

Authors:  Imtiaz Khan; Aliya Ibrar; Sumera Zaib
Journal:  Top Curr Chem (Cham)       Date:  2021-01-05

2.  Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds.

Authors:  Shengfei Jin; Hang T Dang; Graham C Haug; Ru He; Viet D Nguyen; Vu T Nguyen; Hadi D Arman; Kirk S Schanze; Oleg V Larionov
Journal:  J Am Chem Soc       Date:  2020-01-10       Impact factor: 15.419

3.  Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.

Authors:  Hidenori Ochiai; Yuta Uetake; Takashi Niwa; Takamitsu Hosoya
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-26       Impact factor: 15.336

4.  Ni-Catalyzed Reductive Liebeskind-Srogl Alkylation of Heterocycles.

Authors:  Yuanhong Ma; Jose Cammarata; Josep Cornella
Journal:  J Am Chem Soc       Date:  2019-01-22       Impact factor: 15.419

5.  Iridium/N-heterocyclic carbene-catalyzed C-H borylation of arenes by diisopropylaminoborane.

Authors:  Mamoru Tobisu; Takuya Igarashi; Naoto Chatani
Journal:  Beilstein J Org Chem       Date:  2016-04-07       Impact factor: 2.883
  5 in total

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