Literature DB >> 26608846

Base catalysed decomposition of anthracene endoperoxide.

M Klaper1, P Wessig1, T Linker1.   

Abstract

Catalytic amounts of a weak base are sufficient to induce the decomposition of anthracene endoperoxides to anthraquinone. The mechanism has been elucidated by isolation of intermediates in combination with DFT calculations. The whole process is suitable for the convenient generation of hydrogen peroxide under very mild conditions.

Entities:  

Year:  2016        PMID： 26608846     DOI： 10.1039/c5cc08606j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

Review 1.  Rearrangements of organic peroxides and related processes.

Authors:  Ivan A Yaremenko; Vera A Vil'; Dmitry V Demchuk; Alexander O Terent'ev
Journal:  Beilstein J Org Chem       Date:  2016-08-03       Impact factor: 2.883

Review 2.  Journey of anthraquinones as anticancer agents - a systematic review of recent literature.

Authors:  M Shaheer Malik; Reem I Alsantali; Rabab S Jassas; Abdulrahman A Alsimaree; Riyaz Syed; Meshari A Alsharif; Kulkarni Kalpana; Moataz Morad; Ismail I Althagafi; Saleh A Ahmed
Journal:  RSC Adv       Date:  2021-11-05       Impact factor: 4.036

3.  Probing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy.

Authors:  Alen Vizintin; Jan Bitenc; Anja Kopač Lautar; Klemen Pirnat; Jože Grdadolnik; Jernej Stare; Anna Randon-Vitanova; Robert Dominko
Journal:  Nat Commun       Date:  2018-02-14       Impact factor: 14.919

4.  Phenolic Hydrogen Transfer by Molecular Oxygen and Hydroperoxyl Radicals. Insights into the Mechanism of the Anthraquinone Process.

Authors:  Hans-Gert Korth; Peter Mulder
Journal:  J Org Chem       Date:  2020-01-23       Impact factor: 4.354

5.  Syntheses and crystal structures of a nitro-anthracene-isoxazole and its oxidation product.

Authors:  Chun Li; Matthew J Weaver; Michael J Campbell; Nicholas R Natale
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-06-10

6.  Activation of Anthracene Endoperoxides in Leishmania and Impairment of Mitochondrial Functions.

Authors:  Gerald Geroldinger; Matthias Tonner; Werner Fudickar; Sritama De Sarkar; Aishwarya Dighal; Lianet Monzote; Katrin Staniek; Torsten Linker; Mitali Chatterjee; Lars Gille
Journal:  Molecules       Date:  2018-07-10       Impact factor: 4.411
  6 in total

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