| Literature DB >> 26606194 |
Fangna Dai1, Weidong Fan2, Jiahui Bi2, Peng Jiang3, Dandan Liu3, Xirui Zhang2, Huan Lin2, Chuanfang Gong2, Rongming Wang2, Liangliang Zhang2, Daofeng Sun2.
Abstract
A 3D non-interpenetrating porous metal-organic framework [Pb2(H2TCPP)]·4DMF·H2O (Pb-TCPP) (H6TCPP = 5,10,15,20-tetra(carboxyphenyl)porphyrin) was synthesized by employment of a robust porphyrin ligand. Pb-TCPP exhibits a one-dimensional channel possessing fairly good capability of gas sorption for N2, H2, Ar, and CO2 gases, and also features selectivity for CO2 over CH4 at 298 K. Furthermore, Pb-TCPP shows electrocatalytic activity for water oxidation in alkaline solution. It is the first 3D porous Pb-MOF that exhibits both gas adsorption properties and electrocatalytic activity for an oxygen evolution reaction (OER).Entities:
Year: 2016 PMID: 26606194 DOI: 10.1039/c5dt04025f
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390