Literature DB >> 26603589

A [3Fe-3S](3+) cluster with exclusively μ-sulfide donors.

Yousoon Lee1, Ie-Rang Jeon2, Khalil A Abboud1, Ricardo García-Serres3, Jason Shearer4, Leslie J Murray1.   

Abstract

A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.

Entities:  

Year:  2016        PMID： 26603589     DOI： 10.1039/c5cc07813j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Mass spectrometric identification of intermediates in the O2-driven [4Fe-4S] to [2Fe-2S] cluster conversion in FNR.

Authors:  Jason C Crack; Andrew J Thomson; Nick E Le Brun
Journal:  Proc Natl Acad Sci U S A       Date:  2017-04-03       Impact factor: 11.205

2.  Dinitrogen Activation and Functionalization using β-Diketiminate Iron Complexes.

Authors:  Samuel M Bhutto; Patrick L Holland
Journal:  Eur J Inorg Chem       Date:  2019-04-01       Impact factor: 2.524

3.  Isolation of chloride- and hydride-bridged tri-iron and -zinc clusters in a tris(β-oxo-δ-diimine) cyclophane ligand.

Authors:  Dae Ho Hong; Brian J Knight; Vincent J Catalano; Leslie J Murray
Journal:  Dalton Trans       Date:  2019-07-02       Impact factor: 4.390

4.  Reversible Alkyl-Group Migration between Iron and Sulfur in [Fe4S4] Clusters.

Authors:  Mengshan Ye; Alexandra C Brown; Daniel L M Suess
Journal:  J Am Chem Soc       Date:  2022-07-13       Impact factor: 16.383

5.  Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron.

Authors:  Nicholas A Arnet; Sean F McWilliams; Daniel E DeRosha; Brandon Q Mercado; Patrick L Holland
Journal:  Inorg Chem       Date:  2017-07-20       Impact factor: 5.165

6.  Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe-H/B-F bond metathesis.

Authors:  Kevin J Anderton; Brian J Knight; Arnold L Rheingold; Khalil A Abboud; Ricardo García-Serres; Leslie J Murray
Journal:  Chem Sci       Date:  2017-04-11       Impact factor: 9.825
  6 in total

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