Literature DB >> 26587566

Uniaxial magnetic anisotropy of square-planar chromium(II) complexes revealed by magnetic and HF-EPR studies.

Yi-Fei Deng1, Tian Han1, Zhenxing Wang2, Zhongwen Ouyang2, Bing Yin3, Zhiping Zheng4, J Krzystek5, Yan-Zhen Zheng1.   

Abstract

Two mononuclear square-planar Cr(II) complexes are reported, exhibiting field-induced slow magnetic relaxation. The axial zero-field splitting parameter was unambiguously determined by both a high-frequency/field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements. This result represents the first observed single-molecule-magnet behavior in the square planar coordination geometry of any metal ions.

Entities:  

Year:  2015        PMID： 26587566     DOI： 10.1039/c5cc07025b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

Authors:  Jamie M Frost; Katie L M Harriman; Muralee Murugesu
Journal:  Chem Sci       Date:  2015-12-23       Impact factor: 9.825

2.  A cobalt complex with 2,4,6-tris(di-2-pyridylamine)-1,3,5-triazine: antiferromagnetic couple governed single-molecule-magnet behaviour.

Authors:  Hang Gao; Ka Liu; Jin Chang; Juan Zhang
Journal:  RSC Adv       Date:  2021-03-25       Impact factor: 3.361

3.  Revealing redox isomerism in trichromium imides by anomalous diffraction.

Authors:  Amymarie K Bartholomew; Rebecca A Musgrave; Kevin J Anderton; Cristin E Juda; Yuyang Dong; Wei Bu; Su-Yin Wang; Yu-Sheng Chen; Theodore A Betley
Journal:  Chem Sci       Date:  2021-11-03       Impact factor: 9.825

4.  The Origin of Magnetic Anisotropy and Single-Molecule Magnet Behavior in Chromium(II)-Based Extended Metal Atom Chains.

Authors:  Andrea Cornia; Anne-Laure Barra; Vladimir Bulicanu; Rodolphe Clérac; Miguel Cortijo; Elizabeth A Hillard; Rita Galavotti; Alessandro Lunghi; Alessio Nicolini; Mathieu Rouzières; Lorenzo Sorace; Federico Totti
Journal:  Inorg Chem       Date:  2020-01-22       Impact factor: 5.165
  4 in total

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