Literature DB >> 26580021

Synthesis of Perfluorinated Isoquinolinediones through Visible-Light-Induced Cyclization of Alkenes.

Shi Tang1,2, You-Lin Deng1, Jie Li1, Wen-Xin Wang1, Guo-Liang Ding1, Ming-Wei Wang1, Zhu-Ping Xiao1, Ying-Chun Wang1, Rui-Long Sheng3.   

Abstract

A novel visible-light-induced carboperfluoroalkylation of alkenes using perfluoroalkyl iodides and bromides as Rf sources, leading to isoquinoline-1,3-diones, was developed. This method offers rapid entry to perfluorinated isoquinoline-1,3(2H,4H)-diones from N-alkyl-N-methacryloyl benzamides under mild reaction conditions, allowing for the incorporation of a wide variety of perfluorinated groups such as CF3, C3F7, C4F9, C6F13, C8F17, C10F21, and CF2CO2Et.

Entities:  

Year:  2015        PMID: 26580021     DOI: 10.1021/acs.joc.5b01803

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Visible-Light-Promoted Transition-Metal-Free Construction of 3-Perfluoroalkylated Thioflavones.

Authors:  Chunhua Ma; Hui Meng; Xing He; Yuqin Jiang; Bing Yu
Journal:  Front Chem       Date:  2022-07-13       Impact factor: 5.545

2.  Kinetic resolution of racemic allylic alcohols via iridium-catalyzed asymmetric hydrogenation: scope, synthetic applications and insight into the origin of selectivity.

Authors:  Haibo Wu; Cristiana Margarita; Jira Jongcharoenkamol; Mark D Nolan; Thishana Singh; Pher G Andersson
Journal:  Chem Sci       Date:  2020-12-08       Impact factor: 9.825

  2 in total

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