Literature DB >> 26577114

A Rhodium Nanoparticle-Lewis Acidic Ionic Liquid Catalyst for the Chemoselective Reduction of Heteroarenes.

Alena Karakulina1, Aswin Gopakumar1, İsmail Akçok1, Bastien L Roulier1, Thomas LaGrange2, Sergey A Katsyuba3, Shoubhik Das4, Paul J Dyson5.   

Abstract

We describe a catalytic system composed of rhodium nanoparticles immobilized in a Lewis acidic ionic liquid. The combined system catalyzes the hydrogenation of quinolines, pyridines, benzofurans, and furan to access the corresponding heterocycles, important molecules present in fine chemicals, agrochemicals, and pharmaceuticals. The catalyst is highly selective, acting only on the heteroaromatic ring, and not interfering with other reducible functional groups.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lewis acids; hydrogenation; ionic liquids; nanoparticle catalysis; quinolines

Year:  2015        PMID： 26577114     DOI： 10.1002/anie.201507945

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Tuning the Catalytic Performance of Cobalt Nanoparticles by Tungsten Doping for Efficient and Selective Hydrogenation of Quinolines under Mild Conditions.

Authors:  Marta Puche; Lichen Liu; Patricia Concepción; Iván Sorribes; Avelino Corma
Journal:  ACS Catal       Date:  2021-06-18       Impact factor: 13.700

2.  A sulfur-tethering synthesis strategy toward high-loading atomically dispersed noble metal catalysts.

Authors:  Lei Wang; Ming-Xi Chen; Qiang-Qiang Yan; Shi-Long Xu; Sheng-Qi Chu; Ping Chen; Yue Lin; Hai-Wei Liang
Journal:  Sci Adv       Date:  2019-10-25       Impact factor: 14.136

3.  Chemoselective hydrogenation of heteroarenes and arenes by Pd-Ru-PVP under mild conditions.

Authors:  Chandan Chaudhari; Katsutoshi Sato; Yoshihide Nishida; Tomokazu Yamamoto; Takaaki Toriyama; Syo Matsumura; Yasuyuki Ikeda; Kenji Terada; Naoya Abe; Kohei Kusuda; Hiroshi Kitagawa; Katsutoshi Nagaoka
Journal:  RSC Adv       Date:  2020-12-15       Impact factor: 4.036

4.  One-Pot Route from Halogenated Amides to Piperidines and Pyrrolidines.

Authors:  Qiao Song; Sheng Wang; Xiangui Lei; Yan Liu; Xin Wen; Zhouyu Wang
Journal:  Molecules       Date:  2022-07-22       Impact factor: 4.927

5.  Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes.

Authors:  Feng Chen; Basudev Sahoo; Carsten Kreyenschulte; Henrik Lund; Min Zeng; Lin He; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-07-12       Impact factor: 9.825

6.  Selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes and methylamines from cyclic amines and CO2/H2 catalyzed by an ionic liquid-Pd/C system.

Authors:  Ruipeng Li; Yanfei Zhao; Huan Wang; Junfeng Xiang; Yunyan Wu; Bo Yu; Buxing Han; Zhimin Liu
Journal:  Chem Sci       Date:  2019-09-03       Impact factor: 9.825

7.  Atomically dispersed Ir/α-MoC catalyst with high metal loading and thermal stability for water-promoted hydrogenation reaction.

Authors:  Siwei Li; Ruochen Cao; Mingquan Xu; Yuchen Deng; Lili Lin; Siyu Yao; Xuan Liang; Mi Peng; Zirui Gao; Yuzhen Ge; Jin-Xun Liu; Wei-Xue Li; Wu Zhou; Ding Ma
Journal:  Natl Sci Rev       Date:  2021-02-10       Impact factor: 17.275

8.  A General Catalyst Based on Cobalt Core-Shell Nanoparticles for the Hydrogenation of N-Heteroarenes Including Pyridines.

Authors:  Kathiravan Murugesan; Vishwas G Chandrashekhar; Carsten Kreyenschulte; Matthias Beller; Rajenahally V Jagadeesh
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-17       Impact factor: 16.823
  8 in total

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