Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology.

A continuous shape measures analysis of the coordination polyhedra of a host of transition metal complexes with bi- and multidentate ligands discloses the distortion pathway associated with each particular topology of the chelate rings formed. The basic parameter that controls the degree of distortion is the metal-donor atom bond distance that induces nonideal bond angles due to the rigidity of the ligands. Thus, the degree of distortion within each family of complexes depends on the atomic size, on which the high- or low-spin state has a large effect. Special attention is therefore paid to several spin-crossover systems and to the enhanced distortions that go along with the transition from low- to high-spin state affected by temperature, light, or pressure. Several families of complexes show deviations from the expected distortion pathways in the high-spin state that can be associated to the onset of intermolecular interactions such as secondary coordination of counterions or solvent molecules. Also, significant displacement of counterions in an extended solid may result from the changes in metal-ligand bond distances when ligands are involved in intermolecular hydrogen bonding.